195374-95-9

Upstream product

• 6142-95-6 phenylpropargyl aldehyde diethyl acetal 
• 69010-01-1 (2R*,3S*)-1,4-bis(benzyloxy)butane-2,3-diol 

Downstream Products

• 210104-38-4 (S)-3-((1R,2S)-3-Benzyloxy-1-benzyloxymethyl-2-hydroxy-propoxy)-5-phenyl-pent-4-ynethioic acid S-tert-butyl ester 
• 80183-15-9 (2R,3R)-1,4-bis(benzyloxy)-2,3-epoxy butane 
• 101703-83-7 1,3,4-tribenzyloxy-D-erythritol 
• 210104-41-9 (2S,3R)-3-Azido-1,4-bis-benzyloxy-butan-2-ol 
• 134964-81-1 (2S,3R)-3-Amino-1,4-bis-benzyloxy-butan-2-ol 
• 210104-32-8 (2R,3S)-1,4-Bis-benzyloxy-3-methoxymethoxy-butan-2-ol 
• 107938-43-2 (2S,3S)-2-Amino-1,4-di-O-benzylthreitol 

Relevant academic research and scientific papers

Deracemization of anti-1,2-diols leading to trans-epoxides via oxazaborolidine-mediated enantiomer-differentiating ring-cleavage of acetal derivatives

An enantioconvergent transformation of racemic anti-1,2-diols to enantiomerically enriched (71-96% ee) trans-epoxides is realized via chiral oxazaborolidine-mediated enantiomer-differentiating ring-cleavage reaction of the acetal derivatives.

Desymmetrization of meso-1,2-diols via chiral oxazaborolidine-mediated ring-cleavage of acetal derivatives with silyl ketene S,O-acetal

Desymmetrization of meso-1,2-diols leading to enantiomerically enriched MOM and MEM ethers is realized via chiral oxazaborolidine-mediated enantioselective ring-cleavage reaction of the acetal derivatives with silyl ketene S,O-acetal.