195438-61-0Relevant academic research and scientific papers
PHOTOINDUZIERTE ADDITION VON R3SiH AN (η4-BUTADIEN)TRICARBONYLEISEN
Fischler, Ingrid,Grevels, Friedrich-Wilhelm
, p. 181 - 190 (1981)
Irradiation of a mixture of 1,3-dienes, silanes, and pentacarbonyliron leads to mixtures of isomeric hydrosilylation products.The reaction is shown to proceed via the intermediate formation of (η3-anti-butenyl)tricarbonyliron-trialkylsilicon complexes which are accessible by photoinduced addition of R3SiH to (η4-butadiene)tricarbonyliron and, upon thermal decomposition, yield similar mixtures of isomeric butenyltrialkylsilicon derivatives.
