Journal of Organometallic Chemistry p. 181 - 190 (1981)
Update date:2022-08-05
Topics:
Fischler, Ingrid
Grevels, Friedrich-Wilhelm
Irradiation of a mixture of 1,3-dienes, silanes, and pentacarbonyliron leads to mixtures of isomeric hydrosilylation products.The reaction is shown to proceed via the intermediate formation of (η3-anti-butenyl)tricarbonyliron-trialkylsilicon complexes which are accessible by photoinduced addition of R3SiH to (η4-butadiene)tricarbonyliron and, upon thermal decomposition, yield similar mixtures of isomeric butenyltrialkylsilicon derivatives.
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