195614-79-0

Upstream product

• 100-42-5 styrene 
• 125475-73-2 bis(acetonitrile)bromo(pentafluorophenyl)palladium(II) 

Downstream Products

• 195614-81-4 [Pd(η(3)-CHPhCH2C6F5)(PPh3)2]Br 
• 80365-31-7 (E)-1,2,3,4,5-pentafluoro-6-styrylbenzene 
• 22557-13-7 1,2,3,4,5-pentafluoro-6-phenethylbenzene 
• 80365-31-7 (Z)-1,2,3,4,5-pentafluoro-6-styrylbenzene 
• 244135-09-9 ((CH₃C₆H₉C₃H₅)PdBr)2 
• 7440-05-3 palladium 
• 244181-98-4 ((CH₃C₆H₉C₃H₅)PdBr)2 

Relevant academic research and scientific papers

Involvement of intramolecular hydride transfer in the formation of alkanes from palladium alkyls

Intramolecular hydride transfer in a dimer between Pd atoms and reductive elimination of H and a benzyl moiety to give PhCH2CH2C6F5 (3) is the main decomposition pathway for the hydrido species generated from the η3-benzylpalladium derivative [Pd2(μ-Br)2(η3-CHPhCH2C 6F5)2] (1). The commonly accepted decomposition of the palladium hydride to give Pd(0) and HX, followed by acid attack on 1 to produce the alkane, is ruled out in this case.