195873-73-5Relevant academic research and scientific papers
Synthesis of differentially protected myo- and chiro-inositols from D-xylose: Stereoselectivity in intramolecular SmI2-promoted pinacol reactions
Luchetti, Giovanni,Ding, Kejia,Kornienko, Alexander,D'Alarcao, Marc
scheme or table, p. 3148 - 3154 (2009/04/07)
Methods for the enantioselective conversion of D-xylose into differentially protected myo-inositol and L-chiro-inositol have been developed. The key transformation is a highly diastereoselective intramolecular SmI 2-promoted pinacol coupling. T
Enantio- and diastereodivergent synthetic route to multifarious cyclitols from D-xylose via ring-closing metathesis
Luchetti, Giovanni,Ding, Kejia,D'Alarcao, Marc,Kornienko, Alexander
experimental part, p. 3142 - 3147 (2009/04/06)
Short stereoselective syntheses of various cyclitols, including the derivatives of conduritol B, conduritol F, myo-inositol, and chiro-inositol have been accomplished. The key steps in the syntheses are a ring-closing metathesis process and a diastereodiv
Synthesis of cyclitols via ring-closing metathesis
Kornienko, Alexander,D'Alarcao, Marc
, p. 827 - 829 (2007/10/03)
A convenient synthesis of enantiomerically pure and differentially protected L-chiro- and myo-inositols as well as conduritols B and F from 2,3,4-tri-O-benzyl-D-xylopyranose via ring-closing metathesis is reported. The facile synthesis of conduritol B con
