102997-58-0

Basic information

• Product Name: (1R,2R,3S)-tris(phenylmethoxy)-6S-hydroxy-cyclohex-4-ene
• Synonyms: (1R,2R,3S)-tris(phenylmethoxy)-6S-hydroxy-cyclohex-4-ene
• CAS NO: 102997-58-0
• Molecular Weight: 416.517
• Mol File: 102997-58-0.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: (1R,2R,3S)-tris(phenylmethoxy)-6S-hydroxy-cyclohex-4-ene(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,2R,3S)-tris(phenylmethoxy)-6S-hydroxy-cyclohex-4-ene(102997-58-0)
• EPA Substance Registry System: (1R,2R,3S)-tris(phenylmethoxy)-6S-hydroxy-cyclohex-4-ene(102997-58-0)

Safety Data

• Hazardous Substances Data: 102997-58-0(Hazardous Substances Data)

Upstream product

• 2595-06-4 methyl 2,3,4-tri-O-benzyl-6-O-trityl-α-D-glucopyranoside 
• 53008-65-4 methyl 2,3,4-tri-O-benzyl-D-glucopyranoside 
• 97-30-3 methyl-alpha-D-glucopyranoside 
• 18311-26-7 methyl 6-O-trityl-α-D-glucopyranoside 
• 195873-65-5 (2S,3R,4S)-2,3,4-Tris-benzyloxy-hex-5-enal 
• 1826-67-1 vinyl magnesium bromide 
• 1092498-81-1 (1S,4S,5R,6R)-4,5,6-tris(benzyloxy)cyclohex-2-enyl 4-nitrobenzoate 
• 85716-43-4 methyl 6-deoxy-6-iodo-2,3,4-tri-O-benzyl-α-D-glucopyranoside 
• 195873-64-4 3,4,5-tri-O-benzyl-1,2-dideoxy-D-xylohept-1-enitol 
• 18039-26-4 2,3,4-tri-O-benzyl-D-xylopyranose 
• 606930-14-7 (2S,3R,4S)-2,3,4-tris-benzyloxy-5-hydroxycyclohexan-1-one 
• 85716-44-5 methyl 2,3,4-tri-O-benzyl-α-d-xylo-hex-5-enopyranoside 
• 195873-73-5 (3S,4R,5R)-tribenzyloxy-(6S)-hydroxyocta-1,7-diene 
• 85798-11-4 (4S,5R,6S)-4,5,6-tris-benzyloxycyclohex-2-en-1-one 

Downstream Products

• 157494-41-2 2-((1R,4S,5R,6R)-4,5,6-Tris-benzyloxy-cyclohex-2-enyl)-isoindole-1,3-dione 
• 126661-83-4 cyclophellitol 
• 139402-99-6 (1S,2S,3R,4S,5R,6R)-2,3,4,5-tetrahydroxy-6-(hydroxymethyl)cyclohexyl methanesulfonate 
• 906748-02-5 (1S,2R,3S,4S,5R,6S)-2,3,4,5-tetrakis(benzyloxy)-6-[(benzyloxy)methyl]cyclohexanol 
• 214411-20-8 (1S,2S,3R,4S,5R,6R)-2,3,4,5-tetrakis(benzyloxy)-6-[(benzyloxy)methyl]cyclohexyl methanesulfonate 
• 906641-07-4 (1S,2R,3S,4S,5R,6R)-2,3,4-tris(benzyloxy)-5-[(4-methoxybenzyl)oxy]-7-oxabicyclo[4.1.0]heptane 
• 214203-47-1 (1R,2S,3R,4R,5S,6R)-2,3,4-tris(benzyloxy)-6-(hydroxymethyl)-5-[(4-methoxybenzyl)oxy]cyclohexanol 
• 214203-48-2 1-methoxy-4-[[(1S,2R,3R,4S,5R,6S)-2,3,4,5-tetrakis(benzyloxy)-6-[(benzyloxy)methyl]-1-cyclohexyl]oxymethyl]benzene 
• 24558-77-8 3,4,5,6-tetra-O-benzyl inositol 
• 1092498-80-0 (1R,4S,5R,6R)-4,5,6-tris(benzyloxy)cyclohex-2-enyl 4-nitrobenzoate 
• 1035456-87-1 2-azido-3,4,6-tri-O-benzyl-2-deoxy-D-α-glucopyranosyI-(1-6)-3,4,5-tri-O-benzyl-1,2-didehydro-1,2-dideoxy-D-myo-inositol 
• 6090-95-5 (+)-(1R,2R,3S,4S,5R,6S)-2,3,4,5-tetraol-7-oxabicyclo[4.1.0]heptane 
• 151557-55-0 ((1R,2S,3R,4R,5S,6S)-2,3,4-Tris-benzyloxy-5,6-dihydroxy-cyclohexyl)-acetic acid ethyl ester 
• 151557-65-2 (3aS,4S,5R,6S,7R,7aS)-4,5,6-Tris-benzyloxy-7-iodo-hexahydro-benzofuran-2-one 

Relevant articles and documents

Synthesis of cyclitols via ring-closing metathesis

A convenient synthesis of enantiomerically pure and differentially protected L-chiro- and myo-inositols as well as conduritols B and F from 2,3,4-tri-O-benzyl-D-xylopyranose via ring-closing metathesis is reported. The facile synthesis of conduritol B con

Synthesis of cyclophellitol utilizing a palladium chloride mediated-ferrier-II rearrangement

Cyclophellitol and its C3-epimer have been synthesized from 5-enoglucopyranoside and 5-enomannopyranoside, respectively. The carbocyclic skeleton was constructed through a Ferrier-II reaction meditated by PdCl 2.

An effective strategy for the synthesis of 6-O-(2-amino-2-deoxy-α-D-glucopyranosyl)-D-chiro- and -D-myo-inositol 1-phosphate related to putative insulin mimetics

Two glycosylinositol phosphates related to putative insulin mimetics, 6-O-(2-amino-2-deoxy-α-D-glucopyranosyl)-D-chiro-inositol 1-phosphate (1) and 6-O-(2-amino-2-deoxy-α-D-glucopyranosyl)-D-myo-inositol 1-phosphate (2), have been synthesized from selectively protected and enantiomerically pure D-chiro- and myo-inositol derivatives. The D-chiro-inositol unit was prepared in a multigram scale from D-glucose using the Ferrier's carbocyclization route, and it was transformed into the corresponding myo epimer by an oxidation-reduction sequence. The trichloroacetimidate method was applied efficiently for the key glycosylation of the inositol derivatives.