195874-16-9

Basic information

• Product Name: (2R,5S)-10-ethoxycarbonyl-11-oxo-2,8,9-triphenyl-1,8-diaza-3,7-dioxa-tricyclo[6.3.0^1,5.0^6,10]undecane
• CAS NO: 195874-16-9
• Molecular Weight: 470.525
• Mol File: 195874-16-9.mol

Chemical Properties

• CAS DataBase Reference: (2R,5S)-10-ethoxycarbonyl-11-oxo-2,8,9-triphenyl-1,8-diaza-3,7-dioxa-tricyclo[6.3.0^1,5.0^6,10]undecane(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,5S)-10-ethoxycarbonyl-11-oxo-2,8,9-triphenyl-1,8-diaza-3,7-dioxa-tricyclo[6.3.0^1,5.0^6,10]undecane(195874-16-9)
• EPA Substance Registry System: (2R,5S)-10-ethoxycarbonyl-11-oxo-2,8,9-triphenyl-1,8-diaza-3,7-dioxa-tricyclo[6.3.0^1,5.0^6,10]undecane(195874-16-9)

Safety Data

• Hazardous Substances Data: 195874-16-9(Hazardous Substances Data)

Upstream product

• 1137-96-8 (Z)-N-benzylideneaniline oxide 
• 166765-36-2 (2R,5S)-7-ethoxycarbonyl-8-oxo-2-phenyl-1-aza-3-oxa-bicyclo[3.3.0]oct-6-ene 

Relevant articles and documents

Functionalised pyrrolidinones derived from (S)-pyroglutamic acid by cycloaddition reactions

The α,β-unsaturatcd bicyclic lactams 3a,c, prepared from (S)-pyroglutamic acid, are useful substrates for cycloaddition reactions, giving excellent regio- and diastereocontrol; however, lactam 3c has very superior reactivity with several dienes and dipoles under mild reaction conditions.