19613-06-0Relevant articles and documents
Electrochemical Functionalization of White Phosphorus
Budnikova, Y. H.,Kargin, Y. M.,Sinyashin, O. G.
, p. 565 - 568 (2007/10/03)
An electrochemical method, based on the joint action of nucleophilic and electrophilic reagents on P4, is proposed in order to utylize white phosphorus in the formation of the esters of phosphorus acids.
Nature of Phenoxides of Phosphorus(V)
Malhotra, K. C.,Sharma, Neeraj
, p. 343 - 345 (2007/10/02)
Compounds of composition P(OC6H5)nCl5-n (n=1->5) have been prepared by the reaction of phosphorus(V) chloride and phenol in appropriate molar ratio in carbon tetrachloride under different experimental conditions.Molecular weight and ir spectral studies show them to be monomers.Double phenoxides of composition M', (M=P; M'=Li, Na or K) have also been prepared by reacting alkali metal phenoxides and phosphorus pentaphenoxide in 1:1 molar ratio which is supported by conductometric titrations in phenol.Reactions with acetyl chloride and hydrogen chloride to get back the original phosphorus chlorides have also been attempted.