19635-06-4Relevant articles and documents
Nickel-catalyzed intermolecular carboiodination of alkynes with aryl iodides
Takahashi, Toshifumi,Kuroda, Daiki,Kuwano, Toru,Yoshida, Yuji,Kurahashi, Takuya,Matsubara, Seijiro
, p. 12750 - 12753 (2018)
Nickel-catalyzed intermolecular carboiodination of alkynes with aryl iodides to form highly substituted and functionalized alkenyl iodides has been developed. The reaction involves radical-mediated formal alkyne insertion into the carbon-nickel bond and c
Synthesis of isomeric benchrotrenic alkenes by Ti-induced carbonyl coupling reaction
Besancon, J.,Szymoniak, J.,Moise, C.
, p. 325 - 330 (2007/10/02)
The benchrotrenic ketones BctCOR (1) (Bct: Cr(CO)3C6H5; R = CH3 (a), C2H5 (b), n-C3H7 (c), n-C4H9 (d) undergo reductive alkene coupling reaction when treated with TiCl3/Li.The two isomeric forms of Bct(R)C=C(R)Bct (2) were isolated in the ratio Z/E = ca. 3:1.Decomplexation of 2 by iodine gave quantitatively the corresponding isomeric alkyl stilbenes C6H5(R)C=C(R)C6H5 (3).
Stereochemistry and Side Products in Reductive Coupling of Alkyl Aryl Ketones to 1,2-Dialkyl-1,2-diarylethylenes
Leimner, Juergen,Weyerstahl, Peter
, p. 3697 - 3705 (2007/10/02)
The reductive coupling of alkyl aryl ketones 1 - 3 and 7 - 9 by low valent titanium salts yields predominantly the (Z)-isomers of 11 - 13 and 17 - 19.Evidence is given by 1H NMR spectroscopy.This behavior can be explained by ?-complex formation of phenyl rings with Ti0.Severe steric hindrance, however, favors the (E)-isomers ( -> 14 and 15).Donor groups in p-position, particularly, give increasing amounts of pinacols, 23 - 27, which undergo rearrangement to the ketones 28 and 29.