196702-69-9Relevant academic research and scientific papers
Syntheses of optically active γ-ketothiols and the esters by lipase-catalyzed hydrolysis via α-acetylthiomethylation of ketones
Izawa, Tomohiko,Terao, Yoshiyasu,Suzuki, Kunio
, p. 2645 - 2648 (1997)
The α-acetylthiomethylation of ketones was achieved by the reaction of ketones or the enamines with N,N-bis-(acetylthiomethyl)-p-chloroaniline in the presence of trifluoroacetic acid. The resulting thiolesters were hydrolyzed enantioselectively by catalys
