19684-46-9

Upstream product

• 2043-61-0 cyclohexanecarbaldehyde 
• 513-42-8 3-hydroxy-2-methyl-1-propene 
• 20498-55-9 3-nitroso-1-oxa-3-aza-spiro[4.5]decan-2-one 
• 19736-55-1 Methallyloxymethylencyclohexan 

Downstream Products

• 1070859-45-8 C₁₅H₂₇N 

Relevant academic research and scientific papers

Consecutive borylcupration/C-C coupling of ?-alkenyl aldehydes towards diastereoselective 2-(borylmethyl)cycloalkanols

Copper(i) catalyzes the borylative cyclization of ?-alkenyl aldehydes through chemo- and regioselective addition of Cu-B to C?C and concomitant intramolecular 1,2-addition of Cu-C on C?O. The products are formed in an exclusive diastereoselective manner and computational analysis identifies the key points for the observed chemo- and diastereoselectivity.

PREPARATION OF PRECURSORS OF CARBENES OF CAAC TYPE AND PREPARING SAID CARBENES THEREFROM

Precursors of carbenes of CAAC type (Cyclic)(Alkyl)(Amino)(Carbenes) are prepared and carbenes are produced therefrom; novel synthesis intermediates are provided for preparing the precursors of CAAC-type carbenes.