19711-56-9

Upstream product

• 134753-15-4 2-Methyl-thiobenzoic acid S-(4-tert-butyl-phenyl) ester 
• 35779-04-5 1-tert-butyl-4-iodobenzene 
• 137-06-4 2-thiocresol 
• 615-37-2 ortho-methylphenyl iodide 
• 95-46-5 2-methylphenyl bromide 
• 2396-68-1 4-t-butylbenzenethiol 
• 15084-51-2 4-tert-butylbenzenesulfonyl chloride 
• 5495-80-7 2-((4-tert-butylphenyl)thio)benzoic acid 

Relevant academic research and scientific papers

Electrochemistry Enabled Nickel-Catalyzed Selective C?S Bond Coupling Reaction

This work describes an electrochemical enabled nickel-catalyzed chemoselective C?S bond coupling protocol for the production of aryl sulfides and sulfones. By simply switching the nickel catalysts and electrodes, this electrochemical C?S bond coupling has demonstrated excellent redox activity, scalability and sustainability. Furthermore, the mechanism for this electrochemical cross-coupling reaction has been investigated.

CN and CS bond forming cross coupling in water with amphiphilic resin-supported palladium complexes

Catalytic CN and CS bond forming reactions of haloarenes with secondary amines and benzenethiols were achieved in water under heterogeneous conditions by the use of immobilized palladium complexes coordinated with the amphiphilic polystyrenepoly( ethylene glycol) resin-supported di(tert-butyl)phosphane ligand to afford aryl(dialkyl)amines and diaryl sulfides in high yield.

Copper-Catalyzed Cross-Coupling of Aryl Halides and Thiols Using Microwave Heating

The copper-catalyzed cross-coupling of aryl halides and thiols using microwave heating is described.

Nickel-catalysed Decarbonylation of Thioesters

A new method of synthesis of vinyl aryl sulphides and diaryl sulphides from α,β-unsaturated and aroyl thioesters by low-valent nickel-mediated decarbonylation is presented.