19737-36-1Relevant academic research and scientific papers
Synthetic and kinetic aspects of nickel-catalysed amination of allylic alcohol derivatives
Bricout, Herve,Carpentier, Jean-Francois,Mortreux, Andre
, p. 1073 - 1084 (2007/10/03)
The design of efficient nickel-based catalytic systems for coupling of diethylamine (1) with esters and ether derivatives of allyl alcohol (2a-c) and related allyl-substituted compounds (4a-e) is reported. Special attention is paid to solvent and salt effects on catalytic activities and kinetic profiles for the formation of allyllamines. The results are discussed in terms of the influence of some reaction parameters (polarity, ion exchange processes, substrate) on the rate determining step of the catalytic cycle.
Palladium-Catalyzed Double and Single Carbonylation of Aryl Halides and Allylic Compounds
Yamamoto, Akio
, p. 433 - 446 (2007/10/02)
After a brief introduction summarizing the author's previous work concerning the double carbonylation of aryl halides catalyzed by palladium complexes, newly found catalytic processes (1) for converting allylic formates and chlorides into β,γ-unsaturated acids and (2) the double carbonylation of allylic chlorides to β,γ-unsaturated α-keto amides are described.Mechanisms which reasonably account for the catalytic processes are proposed on the basis of studies concerning the properties of the organopalladium complexes.
