19755-32-9Relevant academic research and scientific papers
A convenient one-pot synthesis of 1,2-azaphospholanium salts
Aladzheva, Inga M.,Lobanov, Dmitrii I.,Bykhovskaya, Ol'ga V.,Petrovskii, Pavel V.,Lyssenko, Konstantin A.,Mastryukova, Tatyana A.
, p. 596 - 602 (2003)
A novel facile one-pot synthesis of the 1,2-azaphospholanes by intramolecular alkylation of 3-halopropyl amides of tricoordinate phosphorus has been suggested. Using this method, a series of the differently N-substituted 1,2-azaphospholanium salts were sy
Phosphorus-based functional groups as hydrogen bonding templates for rotaxane formation
Ahmed, Rehan,Altieri, Andrea,DSouza, Daniel M.,Leigh, David A.,Mullen, Kathleen M.,Papmeyer, Marcus,Slawin, Alexandra M. Z.,Wong, Jenny K. Y.,Woollins, J. Derek
, p. 12304 - 12310 (2011/10/01)
We report on the use of the hydrogen bond acceptor properties of some phosphorus-containing functional groups for the assembly of a series of [2]rotaxanes. Phosphinamides, and the homologous thio- and selenophosphinamides, act as hydrogen bond acceptors t
Photoinduced hydrophosphinylation of alkenes with diphenylphosphine oxide
Kawaguchi, Shin-ichi,Nomoto, Akihiro,Sonoda, Motohiro,Ogawa, Akiya
scheme or table, p. 624 - 626 (2011/02/28)
Photoinduced hydrophosphinylation of alkenes with diphenylphosphine oxide took place regioselectively affording the corresponding phosphine oxide in good yields. This hydrophosphinylation is of simple operation and widely tolerant to a variety of the functionalities.
Polymer bound Pd(0) phosphine catalyst for homogeneous catalysis
Koshti, Nirmal,Naik, Shubhangi,Parab, Bharat
, p. 852 - 856 (2007/10/03)
Facile synthesis of water-soluble polymer bound Pd(0) phosphine catalyst is described. This recyclable polymeric catalyst is soluble in aqueous or aqueous/organic media and has high activity in nucleophilic allylic substitution, Heck reaction and hydrogenation.
Asymmetric Michael addition catalyzed by D-glucose-based azacrown ethers
Novák,Tatai,Bakó,Czugler,Keglevich,Toke
, p. 424 - 426 (2007/10/03)
Novel sugar-based azacrown ethers with phosphinoxido-alkyl side chain (2a-e) have been synthesized. They show significant asymmetric induction as phase transfer catalysts in the Michael addition of 2-nitropropane to chalcone (95% ee) and to 3-fur-2-yl-1-phenyl-propenone (80% ee).
