198407-79-3

Upstream product

• 50-00-0 formaldehyd 

Downstream Products

• 198407-87-3 (2-{1-(tert-Butyl-dimethyl-silanyloxy)-3-[(S)-3-(tert-butyl-dimethyl-silanyloxy)-6-oxo-cyclohex-1-enyl]-prop-2-ynyl}-phenyl)-propynal 
• 198407-85-1 (S)-4-(tert-Butyl-dimethyl-silanyloxy)-2-{3-(tert-butyl-dimethyl-silanyloxy)-3-[2-(3-hydroxy-prop-1-ynyl)-phenyl]-prop-1-ynyl}-cyclohex-2-enone 
• 198407-86-2 {2-[1-(tert-Butyl-dimethyl-silanyloxy)-3-(6-oxo-cyclohex-1-enyl)-prop-2-ynyl]-phenyl}-propynal 
• 198407-84-0 2-{3-(tert-Butyl-dimethyl-silanyloxy)-3-[2-(3-hydroxy-prop-1-ynyl)-phenyl]-prop-1-ynyl}-cyclohex-2-enone 
• 198407-80-6 3-{2-[1-(tert-Butyl-dimethyl-silanyloxy)-prop-2-ynyl]-phenyl}-prop-2-yn-1-ol 

Relevant academic research and scientific papers

First generation of the dienediyne portion of a dienediyne model of the neocarzinostatin chromophore by a McMurry reaction

The first 3→6 type ring-closing dienediyne synthesis by means of a McMurry reaction was realized by converting the ketoaldehyde 20 into the 6-/10-membered bicyclic dienediyne 22. Diastereoselective pinacol couplings 20→23 and 21→24 giving 6-/10-membered b