Tetrahedron Letters p. 7353 - 7356 (1997)
Update date:2022-08-04
Topics:
Rucker, Mark
Brueckner, Reinhard
The first 3→6 type ring-closing dienediyne synthesis by means of a McMurry reaction was realized by converting the ketoaldehyde 20 into the 6-/10-membered bicyclic dienediyne 22. Diastereoselective pinacol couplings 20→23 and 21→24 giving 6-/10-membered b
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