198407-87-3

Upstream product

• 198407-79-3 3-{2-[1-(tert-Butyl-dimethyl-silanyloxy)-3-trimethylsilanyl-prop-2-ynyl]-phenyl}-prop-2-yn-1-ol 
• 198407-80-6 3-{2-[1-(tert-Butyl-dimethyl-silanyloxy)-prop-2-ynyl]-phenyl}-prop-2-yn-1-ol 
• 198407-82-8 tert-Butyl-[1-(2-iodo-phenyl)-prop-2-ynyloxy]-dimethyl-silane 
• 198407-83-9 (4S)-4-[(tert-Butyldimethylsilyl)oxy]-2-iodocyclohex-2-en-1-one 
• 119478-74-9 (S)-4-((tert-butyldimethylsilyl)oxy)cyclohex-2-enone 
• 81758-22-7 1-(2-iodophenyl)prop-2-yn-1-ol 
• 5159-41-1 2-iodobenzyl alcohol 
• 26260-02-6 2-iodobenzaldehyde 
• 198407-85-1 (S)-4-(tert-Butyl-dimethyl-silanyloxy)-2-{3-(tert-butyl-dimethyl-silanyloxy)-3-[2-(3-hydroxy-prop-1-ynyl)-phenyl]-prop-1-ynyl}-cyclohex-2-enone 

Relevant academic research and scientific papers

First generation of the dienediyne portion of a dienediyne model of the neocarzinostatin chromophore by a McMurry reaction

The first 3→6 type ring-closing dienediyne synthesis by means of a McMurry reaction was realized by converting the ketoaldehyde 20 into the 6-/10-membered bicyclic dienediyne 22. Diastereoselective pinacol couplings 20→23 and 21→24 giving 6-/10-membered b