198987-18-7Relevant articles and documents
Sulfur-directed synthesis of enantiopure hydroxy 2-sulfinyl butadienes
Fernandez De La Pradilla, Roberto,Martinez, Maria Victoria,Montero, Carlos,Viso, Alma
, p. 7773 - 7776 (1997)
Epoxy vinyl sulfoxides, generated in situ from sulfinyl chlorohydrins, undergo an efficient base-induced rearrangement to generate enantiopure hydroxy 2-sulfinyl dienes. The chiral sulfur auxillary controls the E-Z stereoselectivity of the trisubstituted