Tetrahedron Letters p. 7773 - 7776 (1997)
Update date:2022-08-03
Topics:
Fernandez De La Pradilla, Roberto
Martinez, Maria Victoria
Montero, Carlos
Viso, Alma
Epoxy vinyl sulfoxides, generated in situ from sulfinyl chlorohydrins, undergo an efficient base-induced rearrangement to generate enantiopure hydroxy 2-sulfinyl dienes. The chiral sulfur auxillary controls the E-Z stereoselectivity of the trisubstituted
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