199008-02-1

Basic information

• Product Name: Benzoic acid (Z)-6-(tert-butyl-dimethyl-silanyloxy)-4-methyl-1-[(E)-1-methyl-3-(2,6,6-trimethyl-cyclohex-1-enyl)-propenyl]-hex-4-en-2-ynyl ester
• Synonyms: Benzoic acid (Z)-6-(tert-butyl-dimethyl-silanyloxy)-4-methyl-1-[(E)-1-methyl-3-(2,6,6-trimethyl-cyclohex-1-enyl)-propenyl]-hex-4-en-2-ynyl ester
• CAS NO: 199008-02-1
• Molecular Weight: 520.828
• Mol File: 199008-02-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzoic acid (Z)-6-(tert-butyl-dimethyl-silanyloxy)-4-methyl-1-[(E)-1-methyl-3-(2,6,6-trimethyl-cyclohex-1-enyl)-propenyl]-hex-4-en-2-ynyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid (Z)-6-(tert-butyl-dimethyl-silanyloxy)-4-methyl-1-[(E)-1-methyl-3-(2,6,6-trimethyl-cyclohex-1-enyl)-propenyl]-hex-4-en-2-ynyl ester(199008-02-1)
• EPA Substance Registry System: Benzoic acid (Z)-6-(tert-butyl-dimethyl-silanyloxy)-4-methyl-1-[(E)-1-methyl-3-(2,6,6-trimethyl-cyclohex-1-enyl)-propenyl]-hex-4-en-2-ynyl ester(199008-02-1)

Safety Data

• Hazardous Substances Data: 199008-02-1(Hazardous Substances Data)

Upstream product

• 117431-83-1 (Z)-tert-butyldimethyl((3-methylpent-2-en-4-yn-1-yl)oxy)silane 
• 14398-40-4 (E)-2-methyl-4-(2,6,6-trimethyl-1-cyclohexenyl)-2-butenal 
• 98-88-4 benzoyl chloride 
• 199007-99-3 (2E,7Z)-9-(tert-Butyl-dimethyl-silanyloxy)-3,7-dimethyl-1-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,7-dien-5-yn-4-ol 

Relevant articles and documents

Alkylidene-2H-pyrans by thermal electrocyclic ring closure of (2Z)-divinylallenals

Electrocyclic ring closure of (2Z)-divinylallenals 8 (including the retroretinal derivative 8a), afforded the corresponding alkylidene-2H-pyrans, under very mild conditions (25°C, 48 h). Initially, an equilibrium between 8a and the kinetic product E-9a wa