200071-04-1Relevant academic research and scientific papers
The stable (phosphino)(silyl)carbene as a useful building block: Synthesis and reactivity of 2-phosphorus-substituted 2H-azirines
Piquet, Valerie,Baceiredo, Antoine,Gornitzka, Heinz,Dahan, Francoise,Bertrand, Guy
, p. 1757 - 1764 (2007/10/03)
[Bis(dicyclohexylamino)phosphino]trimethylsilylcarbene (1) reacts with benzonitrile leading to the corresponding 2-phosphino-2H-azirine 3 in 85% yield. Treatment of 3 with trifluoromethanesulfonic acid, methyl trifluoromethanesulfonate, or elemental sulfu
