167955-65-9

Upstream product

• 100-47-0 benzonitrile 
• 145397-27-9 [Bis(dicyclohexylamino)phosphanyl](trimethylsilyl)diazomethane 
• 152387-46-7 [bis(dicyclohexylamino)phosphino](trimethylsilyl)carbene 

Downstream Products

• 200071-09-6 C₃₇H₆₁N₄PSSi 
• 200071-22-3 C₃₅H₅₈N₃PSSi 
• 200071-11-0 2,2-Bis-dicyclohexylamino-1-methyl-4-phenyl-3-trimethylsilanyl-1H-2λ⁵-[1,5,2]diazaphosphinine-6-thione 
• 200071-04-1 2-[Bis(dicyclohexylamino)thioxophosphoranyl]-3-phenyl-2-trimethylsilyl-2H-azirine 
• 167955-66-0 [2-Bis(dicyclohexylamino)-4-phenyl-2-trimethylsilyl]-2λ⁵-azaphosphete 

Relevant academic research and scientific papers

The stable (phosphino)(silyl)carbene as a useful building block: Synthesis and reactivity of 2-phosphorus-substituted 2H-azirines

[Bis(dicyclohexylamino)phosphino]trimethylsilylcarbene (1) reacts with benzonitrile leading to the corresponding 2-phosphino-2H-azirine 3 in 85% yield. Treatment of 3 with trifluoromethanesulfonic acid, methyl trifluoromethanesulfonate, or elemental sulfu

4-π-electron 4-membered phosphorus heterocycles

The synthesis and reactivity of 4-π-electron 4-membered heterocycles possessing a phosphazene moiety is described.

Synthese eines 2H-Azirins durch -Cycloaddition eines Phosphinocasrbens an ein Nitril und anschliessende Ringerweiterung zu einem 1,2λ5-Azaphosphet

Stichworte: Carbene * Cycloadditionen * Heterocyclen * Phosphorverbindungen