20012-43-5Relevant academic research and scientific papers
Room temperature, metal-free arylation of aliphatic alcohols
Ghosh, Raju,Lindstedt, Erik,Jalalian, Nazli,Olofsson, Berit
, p. 54 - 57 (2014/05/06)
Diaryliodonium salts are demonstrated as efficient arylating agents of aliphatic alcohols under metal-free conditions. The reaction proceeds at room temperature within 90 min to give alkyl aryl ethers in good to excellent yields. Aryl groups with electron
ALKYLATION OF PHENOL BY CHLOROALKANES IN THE PRESENCE OF ALUMINUM PHENOLATE
Kozlikovskii, Ya. B.,Koshchii, V. A.,Butov, S. A.
, p. 128 - 131 (2007/10/02)
The alkylation of phenol by benzyl chloride, 1-chloroadamantane, and tert-butyl chloride in the presence of aluminum phenolate leads to a mixture of the corresponding 2- and 4-alkylphenols and 2,6-dialkylphenols, in which the 2-alkylphenol usually predominates.During the alkylation of phenol by 2-chlorooctane 2- and 4-(3-octyl)phenols and 2- and 3-octyl phenyl ethers are formed in addition to 2- and 4-(2-octyl)phenols.
PREPARATION OF ALKYL-ARYL ETHERS AND THIOETHERS
Downie, Ian M.,Heaney, Harry,Kemp, Graham
, p. 2619 - 2624 (2007/10/02)
A method, which involves no molecular rearrangement, and which is also stereospecific, for the preparation of alkyl-aryl ethers and thioethers is described.Stable alkoxyphosphonium salts, R-O-P(1+)(NMe2)3 PF6(1-), have been prepared and treated with phenols and thiophenols, under basic conditions, to yield the corresponding alkyl-aryl ethers and thioethers respectively.
Solvolysis of N-n-Alkylacridiniums in Phenol and Carboxylic Acids. Primary Carbonium Ions as Possible Intermediates
Katritzky, Alan R.,El-Mowafy, Azzahra M.
, p. 3511 - 3517 (2007/10/02)
N-n-Octyl (1a) and N-n-dodecylacridinium (1b) ions solvolyze in phenol to give mixtures of the n-alkyl phenyl ethers and all the isomeric secondary straight-chain o- and p-alkylphenols.Solvolyses of 1a in carboxylic acids give a mixture of 1-, 2-, 3-, and 4-octyl carboxylic esters.Structures are deduced by GC/MS.Mechanisms are discussed.
