20012-43-5Relevant articles and documents
Room temperature, metal-free arylation of aliphatic alcohols
Ghosh, Raju,Lindstedt, Erik,Jalalian, Nazli,Olofsson, Berit
, p. 54 - 57 (2014/05/06)
Diaryliodonium salts are demonstrated as efficient arylating agents of aliphatic alcohols under metal-free conditions. The reaction proceeds at room temperature within 90 min to give alkyl aryl ethers in good to excellent yields. Aryl groups with electron
PREPARATION OF ALKYL-ARYL ETHERS AND THIOETHERS
Downie, Ian M.,Heaney, Harry,Kemp, Graham
, p. 2619 - 2624 (2007/10/02)
A method, which involves no molecular rearrangement, and which is also stereospecific, for the preparation of alkyl-aryl ethers and thioethers is described.Stable alkoxyphosphonium salts, R-O-P(1+)(NMe2)3 PF6(1-), have been prepared and treated with phenols and thiophenols, under basic conditions, to yield the corresponding alkyl-aryl ethers and thioethers respectively.