200199-15-1

Upstream product

• 95514-03-7 (R)-methyl 3-(tert-butyl(diphenyl)silyloxy)-2-methylpropanoate 
• 127665-69-4 ((2R,3R)-3-((R)-1-((tert-butyldiphenylsilyl)oxy)propan-2-yl)oxiran-2-yl)methanol 
• 127665-68-3 (4S)-5-(tert-butyldiphenylsilyloxy)-4-methyl-2-penten-1-ol 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 95514-04-8 (S)-3-(tert-butyldiphenylsilyloxy)-2-methylpropan-1-ol 
• 200199-14-0 Toluene-4-sulfonic acid (2R,3R)-3-[(R)-2-(tert-butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-oxiranylmethyl ester 

Downstream Products

• 412908-65-7 (3R,4S)-3-(4-Methoxy-benzyloxy)-4-methyl-hex-5-enoic acid (S)-1-[(R)-2-(tert-butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-allyl ester 
• 200199-16-2 (E)-(2S,5S)-6-(tert-Butyl-diphenyl-silanyloxy)-2,5-dimethyl-2-vinyl-hex-3-enoic acid methyl ester 
• 203782-88-1 Toluene-4-sulfonic acid (E)-(2S,5S)-6-(tert-butyl-diphenyl-silanyloxy)-2,5-dimethyl-2-vinyl-hex-3-enyl ester 
• 203782-84-7 (E)-(4S,5R)-6-(tert-Butyl-diphenyl-silanyloxy)-4-methanesulfonyloxy-2,5-dimethyl-hex-2-enoic acid methyl ester 
• 203782-82-5 (E)-(4S,5R)-4-Acetoxy-6-(tert-butyl-diphenyl-silanyloxy)-2,5-dimethyl-hex-2-enoic acid methyl ester 
• 203782-83-6 (E)-(4S,5R)-6-(tert-Butyl-diphenyl-silanyloxy)-4-hydroxy-2,5-dimethyl-hex-2-enoic acid methyl ester 
• 203782-87-0 (E)-(2S,5S)-6-(tert-Butyl-diphenyl-silanyloxy)-2,5-dimethyl-2-vinyl-hex-3-en-1-ol 
• 112763-53-8 (3S,4E,6S)-3,6-dimethyl-7-(p-tolylsulfonyloxy)-3-(tolylsulfonyloxymethyl)hepta-1,4-diene 
• 203782-80-3 Acetic acid (S)-1-[(R)-2-(tert-butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-allyl ester 

Relevant academic research and scientific papers

An olefin metathesis approach towards the solomonamides

A new synthetic strategy directed towards the solomonamides, a novel class of cyclopeptides of marine origin, has been developed utilizing an olefin metathesis reaction to form the [15]-membered ring contained in these natural products. We demonstrated th

Total synthesis of octalactin A via ring-closing metathesis reaction

A new total synthesis of the novel lactone natural product octalactin A is described. The key step involves the facile construction of the eight-membered lactone core via ring-closing metathesis (RCM). This oxocene was elaborated to give the powerful anti

One-pot transformation of p-toluenesulfonates of 2,3-epoxy alcohols into allylic alcohols

A convenient and efficient method for the synthesis of synthetically useful non-racemic allylic alcohols from 4-methylbenzenesulfonates of non- racemic 2,3-epoxy alcohols is described. Satisfactory yields are obtained by treatment of 4-methylbenzenesulfonates of non-racemic 2,3-epoxy alcohols with potassium iodide followed by zinc powder and ammonium chloride in a one-pot manner. The method has been successfully applied to the synthesis of a key building block of C30-C37 botryococcenes.