20049-04-1

Upstream product

• 110-05-4 di-tert-butyl peroxide 
• 100611-61-8 (1-phenyl-cyclopentyl)-acetaldehyde 
• 6196-85-6 1-chloro-1-methylcyclopentane 
• 71-43-2 benzene 
• 1462-03-9 1-methylcyclopentanol 
• 96-37-7 methyl-cyclopentane 
• 622-24-2 2-phenylethyl chloride 
• 110-82-7 cyclohexane 
• 7446-70-0 aluminium trichloride 
• 629624-19-7 (6-chlorohex-1-en-2-yl)benzene 
• 630-19-3 pivalaldehyde 
• 96-22-0 pentan-3-one 
• 693-89-0 1-methylcyclopent-1-ene 
• 24070-77-7 2-methylcyclopentanol 

Downstream Products

• 95979-81-0 1-(1-methyl-cyclopentyl)-4-nitro-benzene 
• 106086-43-5 4-(1-methyl-cyclopentyl)-aniline 
• 1361251-09-3 C₂₁H₂₂O 
• 1361251-02-6 1-(4-[1-methylcyclopentyl]phenyl)-3-phenylpropane 
• 1361251-10-6 C₂₁H₂₄O 
• 1361251-13-9 C₂₁H₂₄⁽²⁾H₂ 
• 1361251-11-7 1-(4-(1-methylcyclopentyl)phenyl)ethan-1-one 

Relevant academic research and scientific papers

Isomerization of the constituents of ion/neutral complexes during the fragmentation of protonated dialkyl-substituted 1,3-diphenylpropanes

The fragmentation of gaseous ion/neutral complexes [R+? C6H5CH2CH2CH2C 6H4-R′] with (i) R = R′ = C4H 9, (ii) R = C4H9 and R

Intramolecular carbolithiation promoted by a DTBB-catalysed chlorine-lithium exchange

The reaction of 6-chlorohex-1-ene 1 with lithium powder and a catalytic amount of 4,4′-di-tert-butylbiphenyl (DTBB, 5% molar) in THF at -78°C gives the corresponding organolithium intermediate 2, which by reaction with different electrophiles affords, aft

Construction of a Sterically Congested Carbon Framework via 5-Hexenyllithium Cyclization. Synthesis of (+/-)-Cuparene.

The naturally occuring sesquiterpene (+/-)-cuparene , which contains two contiguous quaternary centers, is produced in good yield by 5-exo-trig cyclization of the 5-hexenyllithium (2) generated from 6-iodo-3,3-dimethyl-2-(4-methylphenyl)-1-hexene (3) by low temperature lithium-iodine exchange.In contrast, radical mediated cyclization of 3 proceeds via the 6-endo-trig mode to give 1,1-dimethyl-2-(4-methylphenyl)cyclohexane.

Acid-catalyzed Reactions of Aromatic Hydrocarbons with Alkanes and Cycloalkanes. X. Alkylations with Cyclohexane

The complex reaction mixtures of the nonconventional alkylation of benzene with cyclohexane in the presence of Lewis/proton acids and promotors were investigated by gas-liquid chromatography and mass spectrometry.Four representative groups of hydrocarbons were found including cycloalkylbenzenes, substituted indanes or tetralines (C12H16), C1-C6-alkylbenzenes and isomeric biscycloalkyls (C12H22).Their formation is interpreted as a competition between alkylation, (without or with isomerization), ringfission with cycloalkylation or fragmentation, and self-alkylation; phenylcycloalkylcations and phenylalkylcations are the intermediates.