20069-37-8Relevant academic research and scientific papers
Synthesis of 3,5-disubstituted-5,6-dihydro-4h-1,2,5-oxadiazine-6-thiones 1 and 3,5-disubstituted-1,2,4-thiadiazoles
Agirbas, Hikmet,Dueruest, Yasar,Karahasanoglu, Aysun
, p. 173 - 178 (2007/10/03)
3,5-Disubstituted-5,6-dihydro-4H-1,2,5-oxadiazine-6-thiones are prepared by the reaction of acetophenone oximes with thiophosgene. The thermal rearrangement of 3-phenyl-5-(p-tolyl)-5,6-dihydro-4H-1,2,5-oxadiazine-6-thione yields the corresponding 1,2,5-th
SYNTHESIS AND METHYLATION OF SOME 1,2,4-THIADIAZOLE--5-THIONES
Agirbas, Hikmet,Durust, Yasar,Sumengen, Dogan
, p. 321 - 324 (2007/10/02)
3,4-Disubstituted-1,2,4-thiadiazole-5(4H)-thiones (4) have been prepared by the treatment of 3,4-disubstituted-1,2,4-thiadiazole-5(4H)-ones (3) with P4S10.S-Methyl derivatives were obtained from the methylation of 3-substituted-1,2,4-thiadiazole-5(4H)-thi
1,3-Dipolar Cycloaddition Reactions of Nitrilium Betaines with Aryl Thiocyanates and Selenocyanates
Greig, Derek J.,Hamilton, Douglas G.,McPherson, Michael,Paton, R. Michael,Crosby, John
, p. 607 - 612 (2007/10/02)
The carbon-nitrogen triple bond of aryl thiocyanates acts as a dipolarophile in 1,3-dipolar cycloadditions.Reaction with nitrile oxides, nitrile sulphides, and benzonitrile N-phenylimide yields, respectively, 5-arylthio-1,2,4-oxadiazoles, -thidiazoles and -triazoles.Aryl selenocyanates behave similarly forming 5-arylseleno-1,2,4-oxadiazoles and -thiadiazoles from nitrile oxides and sulphides.Divergent pathways are followed by the reactions of secondary amines such as piperidine with 5-arylthio-1,2,4-oxadiazoles and -thidiazoles, the former yielding 5-piperidyl-1,2,4-oxadiazoles and the latter dihydro-1,2,4-thiadiazole-5-thiones.
