200813-52-1Relevant academic research and scientific papers
A practical reagent for the synthesis of substituted hydrazines
Grehn, Leif,Nyasse, Barthelemy,Ragnarsson, Ulf
, p. 1429 - 1432 (1997)
A practical, inexpensive triprotected hydrazine reagent, 2-benzyloxycarbonyl-1 -tert-butoxycarbonyl-1- (4-methylphenylsulfonyl)-hydrazine, 1-Boc-1-Tos-2-Z-hydrazine (2), has been prepared on a 100 pnmol scale and examined with respect to application in st
Regio- and Stereocontrolled Synthesis of 3-Substituted 1,2-Diazetidines by Asymmetric Allylic Amination of Vinyl Epoxide
Rajkumar, Sundaram,Clarkson, Guy J.,Shipman, Michael
supporting information, p. 2058 - 2061 (2017/04/27)
Pd-catalyzed asymmetric allylic amination of rac-vinyl epoxide with unsymmetrical 1,2-hydrazines proceeds with excellent regio- and stereocontrol, which after further ring closure provides differentially protected 3-vinyl-1,2-diazetidines in good yields.
