201008-71-1Relevant articles and documents
Vilsmeier-Haak formylation of 3,5-dimethylpyrazoles
Attaryan,Antanosyan,Panosyan,Asratyan,Matsoyan
, p. 1817 - 1819 (2006)
Formylation of N-alkyl-3,5-dimethyl-1H-pyrazoles according to Vilsmeier-Haak led to the formation of the corresponding 4-formyl derivatives. 3,5-Dimethyl-1H-pyrazole having no substituent on the nitrogen atom failed to undergo formylation at the 4 position under analogous conditions. 3,5-Dimethyl-1H-pyrazole-4-carbaldehyde was synthesized by alkaline hydrolysis of methyl β-(4-formyl-3,5-dimethyl-1H-pyrazol-1-yl)propionate and subsequent heating of the acid thus formed.
Vilsmeier-Haack formylation of 1H-pyrazoles
Badalyan,Akopyan,Attaryan,Asratyan
, p. 793 - 795 (2014/06/09)
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