201139-13-1

Upstream product

• 850223-35-7 (E)-(2S,3R)-2-Amino-3-benzyloxy-octadec-4-en-1-ol 
• 112-76-5 Stearoyl chloride 
• 98-88-4 benzoyl chloride 
• 201139-02-8 Octadecanoic acid ((E)-(1S,2R)-2-benzyloxy-1-hydroxymethyl-heptadec-3-enyl)-amide 
• 201139-12-0 C₃₃H₄₀ClN₂O₉P 

Downstream Products

• 201139-14-2 Benzoic acid (2R,3R,4S,5R,6R)-4-benzyloxy-6-benzyloxymethyl-2-((E)-(2S,3R)-3-benzyloxy-2-octadecanoylamino-octadec-4-enyloxy)-5-hydroxy-tetrahydro-pyran-3-yl ester 

Relevant academic research and scientific papers

Chemoselective glycosidation strategy based on glycosyl donors and acceptors carrying phosphorus-containing leaving groups: A convergent synthesis of ganglioside GM3

A convergent synthesis of ganglioside GM3 has been achieved by capitalizing on three different phosphorus-containing leaving groups, in which the key features involve a chemo- and regioselective α-glycosidation of sialyl phosphite with partially benzylated galactosyl tetramethylphosphorodiamidate by the aid of trifluoromethanesulfonic acid and a traditionally uncommon coupling of an α-sialyl-(2→3)- galactosyl donor with a glucosylceramide building block which has the β-O-linked ceramide prebuilt into the glucose by a diphenyl phosphate method. (C) 2000 Elsevier Science Ltd.

'Armed-disarmed' glycosidation strategy based on glycosyl donors and acceptors carrying phosphoroamidate as a leaving group: A convergent synthesis of globotriaosylceramide

A stereocontrolled synthesis of globotriaosylceramide with three different glycosidic linkages has been accomplished by linear and convergent routes exploiting 'armed-disarmed' glycosidation methodology based on glycosyl donors and acceptors carrying tetramethylphosphoroamidate as a leaving group. In particular, the convergent strategy featuring a coupling of a galactosyl(1→4)-galactosyl donor with a glucosylceramide derivative has proven to be extremely efficient.