201206-41-9

Upstream product

• 403-30-5 1-(4-bromophenyl)-2-fluoroethan-1-one 
• 401-55-8 ethyl bromofluoroacetate 
• 589-87-7 1,4-bromoiodobenzene 
• 99-90-1 para-bromoacetophenone 

Downstream Products

• 1296831-52-1 (R,E)-3-(2-(4-bromophenyl)-1-fluorovinyl)cyclohexanone 
• 1296831-58-7 (S,E)-5-(4-bromophenyl)-4-fluoro-3-methyl-1-phenylpent-4-en-1-one 
• 1296831-74-7 (S,Z)-5-(4-bromophenyl)-4-fluoro-3-methyl-1-phenylpent-4-en-1-one 
• 1296831-22-5 2-(benzo[d]thiazol-2-ylsulfonyl)-1-(4-bromophenyl)-2-fluoroethanone 

Relevant academic research and scientific papers

Nickel-Catalyzed Coupling Reaction of α-Bromo-α-fluoroketones with Arylboronic Acids toward the Synthesis of α-Fluoroketones

A nickel-catalyzed coupling reaction of α-bromo-α-fluoroketones with arylboronic acids was reported, which provides an efficient pathway to access 2-fluoro-1,2-diarylethanones in high yields. We also disclosed the synthesis of the monofluorination agents

OXIME DERIVATIVE, METHOD OF PRODUCING THE SAME AND INSECTICIDE COMPRISING THE SAME AS ACTIVE INGREDIENT

PROBLEM TO BE SOLVED: To provide a compound having excellent insecticidal effect and useful as an active ingredient of an insecticide. SOLUTION: This invention provides an oxime derivative represented by general formula (1) (where Ra, X and n represent definitions described in the specifications) and an insecticide that comprises the same as an active ingredient. COPYRIGHT: (C)2015,JPOandINPIT

Reactions of 1-aryl-2,2-dihalogenoethanone oximes with tetrasulfur tetranitride (S4N4): A general method for the synthesis of 3-aryl-4-halogeno-1,2,5-thiadiazoles

1-Aryl-2,2-dichloro-7, 1-aryl-2,2-dibromo-8, 1-aryl-2-bromo-2-fluoro-9 and 1-aryl-2-chloro-2-fluoroethanone oximes 10 have been prepared by allowing the corresponding ketones to react with hydroxylamine hydrochloride in EtOH at room temperature. Stereoche