201227-90-9

Basic information

• Product Name: GaI₃(P(C₆H₅)(CH₃)2)
• CAS NO: 201227-90-9
• Molecular Weight: 588.586
• Mol File: 201227-90-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: GaI₃(P(C₆H₅)(CH₃)2)(CAS DataBase Reference)
• NIST Chemistry Reference: GaI₃(P(C₆H₅)(CH₃)2)(201227-90-9)
• EPA Substance Registry System: GaI₃(P(C₆H₅)(CH₃)2)(201227-90-9)

Safety Data

• Hazardous Substances Data: 201227-90-9(Hazardous Substances Data)

Upstream product

• 7440-55-3 gallium 
• 7553-56-2 iodine 
• 672-66-2 Dimethyl(phenyl)phosphine 

Relevant articles and documents

Adducts of GaI3 and InI3 with Ph3P and Ph3As

Adducts Ph3PGaI3 and Ph3AsGaI3 obtained by adding the ligands to Et2OGaI3 have been investigated by 71Ga NMR, IR/Raman spectroscopy and X-ray diffraction, Et2OInI3 with Ph3P gives (Ph3P)3(InI3)2. Ph3As yields (Ph3As)3(InI3)2 · H2O as rhombohedral crystals whose structure was solved by X-ray diffraction. Both these indium complexes contain Ph3EInI3 molecules alongside five-coordinate aclducts (Ph3E)2InI3 with the Ph3E ligands attached in axial sites by long and unequal bonds to a planar InI3 unit. Vibrational assignments are made for Ph3PGaI3, Ph3AsGaI3, Ph3EInI3 and (Ph3E)2InI3 (E = P or As).