201593-51-3

Upstream product

• 6564-72-3 2,3,4,6-tetra-O-benzyl-D-glucopyranose 
• 4090-61-3 2-Hydroxy-5,5-dimethyl-2-thioxo-1,3,2-dioxaphosphorinane triethylammonium salt 
• 63053-84-9 1-O-benzoyl-2,3,4,6-tetra-O-benzyl-β-D-glucopyranose 
• 4196-36-5 2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl 4-nitrobenzoate 
• 80300-30-7 1-O-acetyl-2,3,4,6-tetra-O-benzyl-D-glucopyranose 

Downstream Products

• 85422-85-1 1-Deoxy-2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl cyanide 
• 71119-79-4 2,6-anhydro-3,4,5,7-tetra-O-benzyl-D-glycero-D-ido-heptononitrile 
• 82300-67-2 1-deoxy-1-(C-2',4',6'-trimethoxyphenyl) 2,3,4,6-tetra-O-benzyl-β-D-glucopyranoside 
• 82659-52-7 1-(2,3,4,6-O-tetrabenzyl-α-D-glucopyranosyl)-2-propene 
• 108943-81-3 2-(1'-deoxy-2',3',4',6'-tetra-O-benzyl-α-D-glucopyranosyl)furan 

Relevant academic research and scientific papers

Convenient synthesis of S- and Se-(2,3,4,6-tetra-O-benzyl-D-glucopyranosyl)-phosphorothioate, phosphoroselenoate and phosphorodithioate

Organic phosphorothioate 7, phosphoroselenoate 8 and phosphorodithioate 9 were glucosylated with 2,3,4,6-tetra-O-benzyl-D-glucopyranose derivatives 1-6. When the reaction was performed in the presence of boron trifluoride etherate, the products were 5-α-glucosyl and Se-α-glucosyl phosphoroethers 10-12. O-Benzylated glucosyl halides 5-6 with alkylammonium salt of 9 afforded S-β-glucosyl phosphorodithioate 13, which underwent the β?α anomerization by boron trifluoride etherate into more stable α-derivatives.