82659-52-7

Basic information

• Product Name: 1-(2,3,4,6-O-tetrabenzyl-α-D-glucopyranosyl)-2-propene
• Synonyms: 1-(2,3,4,6-O-tetrabenzyl-α-D-glucopyranosyl)-2-propene
• CAS NO: 82659-52-7
• Molecular Weight: 564.722
• Mol File: 82659-52-7.mol
• Article Data: 37

Chemical Properties

• CAS DataBase Reference: 1-(2,3,4,6-O-tetrabenzyl-α-D-glucopyranosyl)-2-propene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(2,3,4,6-O-tetrabenzyl-α-D-glucopyranosyl)-2-propene(82659-52-7)
• EPA Substance Registry System: 1-(2,3,4,6-O-tetrabenzyl-α-D-glucopyranosyl)-2-propene(82659-52-7)

Safety Data

• Hazardous Substances Data: 82659-52-7(Hazardous Substances Data)

Upstream product

• 4196-36-5 2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl 4-nitrobenzoate 
• 762-72-1 allyl-trimethyl-silane 
• 79386-43-9 diphenyl 2,3,4,6-tetra-O-benzyl-α-D-glucosyl phosphate 
• 3879-79-6 methyl 2,3,4,6-tetra-O-benzyl-α-D-glucopyranoside 
• 220662-80-6 2-{[(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)oxy]methyl}benzoic acid 
• 100-39-0 benzyl bromide 
• 24850-33-7 allyltributylstanane 
• 117307-17-2 phenyl 2,3,4,6-tetra-O-benzyl-1-thio-β-D-glucopyranoside sulfoxide 
• 84799-77-9 methyl 2,3,4,6-tetra-O-benzyl-D-glucopyranoside 
• 113533-73-6 (2R,3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-2-((benzyloxy)methyl)-6-(pent-4-en-1-yloxy)tetrahydro-2H-pyran 
• 67773-43-7 2,3,4,6-tetra-O-benzyl-α/β-D-glucopyranosyl bromide 
• 83-87-4 D-glucose pentaacetate 
• 78890-68-3 1-deoxy-2,3,4,6-tetra-O-benzyl-D-glucopyranose 
• 106756-74-5 (2R,3R,4R,5S,6R)-2-allyl-6-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol 

Downstream Products

• 444150-28-1 2-acetamido-2-[3-benzyloxy-4-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranos-1-ylmethyl)benzyl]malonic diethyl ester 
• 444150-22-5 4-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranos-1-ylmethyl)-3-benzyloxybenzoic ethyl ester 
• 444150-18-9 7-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranos-1-yl)-3-ethoxycarbonyl-hepta-3,5-dienoic acid 
• 444150-24-7 1-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranos-1-ylmethyl)-2-benzyloxy-4-hydroxymethylbenzene 
• 444150-26-9 1-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranos-1-ylmethyl)-2-benzyloxy-4-bromomethylbenzene 
• 444150-20-3 4-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranos-1-ylmethyl)-3-hydroxybenzoic ethyl ester 
• 198268-99-4 4-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranos-1-yl)-but-2-enoic ethyl ester 

Relevant articles and documents

8-(Methyltosylaminoethynyl)-1-naphthyl (MTAEN) Glycosides: Potent Donors in Glycosides Synthesis

With 8-(methyltosylaminoethynyl)-1-naphthyl (MTAEN) glycoside as donors, a novel and efficient glycosylation protocol has been established. The MTAEN glycosylation protocol exhibits the merits of shelf-stable donors, mild catalytic promotion conditions, considerably extended substrate scope encompassing both free alcohols, silylated alcohols, nucleobases, primary amides, and C-type nucleophile acceptors, and applicability to various one-pot strategies for highly efficient synthesis of oligosaccharides, such as orthogonal one-pot, single-catalyst one-pot, and acceptor reactivity-controlled one-pot strategies.

Carbon glycoside glycosylated tetravalent platinum compound as well as synthesis method and application thereof

The invention provides a carbon glycoside glycosylated tetravalent platinum compound, a synthesis method and application thereof. R1 and R2 are independently C1-C4 lower alkanes, R3 is glucose, galactose, mannose and ribose, different sugars are used as raw materials, and a series of carbon glycoside glycosylated tetravalent platinum compounds are synthesized through protection and deprotection reaction and metallization reaction of the sugars. The synthesis method is simple, the used raw materials are cheap and easy to obtain, the glycosylated tetravalent platinum compound has the capacity of targeting glucose transporter protein and has potential application value in the field of cancer treatment, introduction of a C-glucosidic bond enables the series of compounds to have the capacity of resisting hydrolysis of beta-glucosidase, and the compound is expected to be applied to the field of oral antitumor drugs.

C -Glycosylation enabled by N -(glycosyloxy)acetamides

The C-glycosylation of C-nucleophiles including allyltrimethylsilane, silyl enol ethers and phenols with N-(glycosyloxy)acetamides as glycosyl donors has been realized. This protocol provides a convenient and practical route for the synthesis of alkyl C-glycosides and aryl 2-deoxy-β-C-glycosides under mild reaction conditions.