201670-54-4

Upstream product

• 106-25-2 Nerol 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 201670-50-0 (Z)-3-Bromo-8-(tert-butyl-diphenyl-silanyloxy)-2,6-dimethyl-oct-6-en-2-ol 
• 201670-52-2 (Z)-8-(tert-Butyl-diphenyl-silanyloxy)-2,6-dimethyl-oct-6-ene-2,3-diol 
• 1528749-25-8 (2Z,6Z)-1-(tert-butyldiphenylsilyloxy)-3,7-dimethyl-8-(2-tetrahydropyranyloxy)octa-2,6-diene 
• 1528749-23-6 (Z)-1-O-tert-butyldiphenylsilyl-3-methyl-6-O-(4-toluenesulfonyl)hexa-2-en-1,6-diol 
• 1528749-22-5 (Z)-1-O-tert-butyldiphenylsilyl-3-methyl-6-O-(4-toluenesulfonyl)hexa-2-en-1,6-diol 
• 930803-78-4 (Z)-1-O-tert-butyldiphenylsilyl-3-methylhexa-2-en-1,6-diol 
• 201670-51-1 (Z)-1-(tert-butyldiphenylsilyloxy)-6,7-epoxy-3,7-dimethylocta-2-ene 
• 139109-03-8 (Z)-1-[(tert-butyldiphenylsilyl)oxy]-3,7-dimethyl-2,6-octadiene 
• 139109-04-9 (Z)-1-[(tert-butyldiphenylsilyl)oxy]-3-methyl-2-hexen-6-al 
• 201670-53-3 (2Z,6Z)-8-(tert-Butyl-diphenyl-silanyloxy)-2,6-dimethyl-octa-2,6-dienoic acid ethyl ester 

Downstream Products

• 1056288-48-2 (2Z,6Z)-1-(tert-butyldiphenylsilyloxy)-8-chloro-3,7-dimethylocta-2,6-diene 
• 1218987-81-5 C₄₇H₆₄O₅SSi 
• 1056289-79-2 (2Z,6Z,10Z,14Z)-9-(benzenesulfonyl)-1-(tert-butyldiphenylsilyloxy)-16-chloro-3,7,11,15-tetramethylhexadeca-2,6,10,14-tetraene 
• 68982-81-0 (2Z,6Z,10Z)-3,7,11,15-tetramethylhexadeca-2,6,10,14-tetraen-1-yl phosphate 
• 201670-63-5 (2E,6Z,10Z)-12-(tert-Butyl-diphenyl-silanyloxy)-6,10-dimethyl-2-[2-((1S,4aS,4bR,8aR,10aR)-2,4b,8,8,10a-pentamethyl-1,4,4a,4b,5,6,7,8,8a,9,10,10a-dodecahydro-phenanthren-1-yl)-ethyl]-dodeca-2,6,10-trienoic acid methyl ester 
• 201670-62-4 (6Z,10Z)-12-(tert-Butyl-diphenyl-silanyloxy)-3-hydroxy-6,10-dimethyl-2-[2-((1S,4aS,4bR,8aR,10aR)-2,4b,8,8,10a-pentamethyl-1,4,4a,4b,5,6,7,8,8a,9,10,10a-dodecahydro-phenanthren-1-yl)-ethyl]-dodeca-6,10-dienoic acid methyl ester 
• 201670-64-6 (2E,6Z,10Z)-12-(tert-Butyl-diphenyl-silanyloxy)-6,10-dimethyl-2-[2-((1S,4aS,4bR,8aR,10aR)-2,4b,8,8,10a-pentamethyl-1,4,4a,4b,5,6,7,8,8a,9,10,10a-dodecahydro-phenanthren-1-yl)-ethyl]-dodeca-2,6,10-trien-1-ol 
• 201670-65-7 tert-Butyl-diphenyl-[(2Z,6Z,10Z)-3,7,11-trimethyl-13-((1S,4aS,4bR,8aR,10aR)-2,4b,8,8,10a-pentamethyl-1,4,4a,4b,5,6,7,8,8a,9,10,10a-dodecahydro-phenanthren-1-yl)-trideca-2,6,10-trienyloxy]-silane 
• 201670-60-2 (6Z,10Z)-12-(tert-Butyl-diphenyl-silanyloxy)-3-hydroxy-6,10-dimethyl-2-methylene-dodeca-6,10-dienoic acid methyl ester 
• 201670-56-6 (4Z,8Z)-10-(tert-Butyl-diphenyl-silanyloxy)-4,8-dimethyl-deca-4,8-dienal 
• 201670-55-5 (4Z,8Z)-10-(tert-Butyl-diphenyl-silanyloxy)-4,8-dimethyl-deca-4,8-dienenitrile 
• 201670-61-3 ((2Z,6Z)-8-Bromo-3,7-dimethyl-octa-2,6-dienyloxy)-tert-butyl-diphenyl-silane 

Relevant academic research and scientific papers

N-GLYCOSYLATION OF PEPTIDES AND PROTEINS

A process for the production of a glycoconjugate by N-glycosylation of a protein or peptide comprising the sequence D/E-X-N-X-S/T, wherein each X is the same or different and is any natural amino acid other than proline, wherein the process comprises reacting the protein or peptide with a polyisoprenyl pyrophosphate of formula (I), or a salt thereof, in the presence of PglB: (I) to produce the glycoconjugate comprising the protein or peptide having a saccharide [SI] linked to the asparagine in the sequence D/E-X-N-X-S/T. Polyisoprenylpyrophosphates used as substrates in the biocatalytic process are also provided, as well as certain glycoconjugates.

Synthesis of tricyclopolyprenols via a radical addition and a stereoselective elimination, part II: (Z)-tricyclopentaprenol, (E,E)- and (Z,Z)-tricyclohexaprenol, (Z,Z,Z)-tricycloheptaprenol

Four tricyclopolyprenols have been synthesised by addition of the isocopalenyl radical either to a 2-methylene-3-hydroxy alkenenitrile (in the case of (E,E)-tricyclohexaprenol) or to a methyl 2-methylene-3-hydroxy alkenoate (in the case of the three (Z)-t