201670-66-8

Upstream product

• 106-24-1 Geraniol 
• 139109-02-7 (E)-6-((tert-butyldiphenylsilyl)oxy)-4-methylhex-4-enal 
• 201670-49-7 (E)-8-(tert-Butyl-diphenyl-silanyloxy)-3-hydroxy-6-methyl-2-methylene-oct-6-enenitrile 
• 139108-85-3 isocopalenyl iodide 
• 139109-03-8 tert-butyl ({[(2E)-3,7-dimethylocta-2,6-dien-1-yl]oxy})diphenylsilane 
• 108-24-7 acetic anhydride 
• 201799-08-8 (E)-8-(tert-Butyl-diphenyl-silanyloxy)-3-hydroxy-6-methyl-2-[2-((1S,4aS,4bR,8aR,10aR)-2,4b,8,8,10a-pentamethyl-1,4,4a,4b,5,6,7,8,8a,9,10,10a-dodecahydro-phenanthren-1-yl)-ethyl]-oct-6-enenitrile 
• 58479-61-1 tert-butylchlorodiphenylsilane 

Downstream Products

• 145773-14-4 tert-Butyl-[(2E,6E)-3,7-dimethyl-9-((1S,4aS,4bR,8aR,10aR)-2,4b,8,8,10a-pentamethyl-1,4,4a,4b,5,6,7,8,8a,9,10,10a-dodecahydro-phenanthren-1-yl)-nona-2,6-dienyloxy]-diphenyl-silane 
• 145663-94-1 (2Z,6E)-8-(tert-Butyl-diphenyl-silanyloxy)-6-methyl-2-[2-((1S,4aS,4bR,8aR,10aR)-2,4b,8,8,10a-pentamethyl-1,4,4a,4b,5,6,7,8,8a,9,10,10a-dodecahydro-phenanthren-1-yl)-ethyl]-octa-2,6-dienylamine 
• 145663-96-3 tert-Butyl-[(2E,6Z)-7-chloromethyl-3-methyl-9-((1S,4aS,4bR,8aR,10aR)-2,4b,8,8,10a-pentamethyl-1,4,4a,4b,5,6,7,8,8a,9,10,10a-dodecahydro-phenanthren-1-yl)-nona-2,6-dienyloxy]-diphenyl-silane 
• 145663-95-2 {(2Z,6E)-8-(tert-Butyl-diphenyl-silanyloxy)-6-methyl-2-[2-((1S,4aS,4bR,8aR,10aR)-2,4b,8,8,10a-pentamethyl-1,4,4a,4b,5,6,7,8,8a,9,10,10a-dodecahydro-phenanthren-1-yl)-ethyl]-octa-2,6-dienyl}-dimethyl-amine 
• 145664-02-4 (2E,6E)-8-(tert-Butyl-diphenyl-silanyloxy)-6-methyl-2-[2-((1S,4aS,4bR,8aR,10aR)-2,4b,8,8,10a-pentamethyl-1,4,4a,4b,5,6,7,8,8a,9,10,10a-dodecahydro-phenanthren-1-yl)-ethyl]-octa-2,6-dienenitrile 
• 145663-93-0 (2Z,6E)-8-(tert-Butyl-diphenyl-silanyloxy)-6-methyl-2-[2-((1S,4aS,4bR,8aR,10aR)-2,4b,8,8,10a-pentamethyl-1,4,4a,4b,5,6,7,8,8a,9,10,10a-dodecahydro-phenanthren-1-yl)-ethyl]-octa-2,6-dienenitrile 

Relevant academic research and scientific papers

Synthesis of tricyclopolyprenols via a radical addition and a stereoselective elimination, part II: (Z)-tricyclopentaprenol, (E,E)- and (Z,Z)-tricyclohexaprenol, (Z,Z,Z)-tricycloheptaprenol

Four tricyclopolyprenols have been synthesised by addition of the isocopalenyl radical either to a 2-methylene-3-hydroxy alkenenitrile (in the case of (E,E)-tricyclohexaprenol) or to a methyl 2-methylene-3-hydroxy alkenoate (in the case of the three (Z)-t

A new synthesis of (E,E)-tricyclohexaprenol

(E,E)-Tricyclohexaprenol has been synthesized by addition of the isocopal-12-en-15-yl radical to a 3-hydroxy-2-methylene alkenenitrile, stereoselective elimination of acetic acid from the acetylated adducts, and reduction of the cyano group into a methyl