201799-08-8Relevant academic research and scientific papers
Synthesis of tricyclopolyprenols via a radical addition and a stereoselective elimination, part II: (Z)-tricyclopentaprenol, (E,E)- and (Z,Z)-tricyclohexaprenol, (Z,Z,Z)-tricycloheptaprenol
Jenn, Thierry,Heissler, Denis
, p. 107 - 118 (2007/10/03)
Four tricyclopolyprenols have been synthesised by addition of the isocopalenyl radical either to a 2-methylene-3-hydroxy alkenenitrile (in the case of (E,E)-tricyclohexaprenol) or to a methyl 2-methylene-3-hydroxy alkenoate (in the case of the three (Z)-t
A new synthesis of (E,E)-tricyclohexaprenol
Jenn, Thierry,Heissler, Denis
, p. 7227 - 7228 (2007/10/02)
(E,E)-Tricyclohexaprenol has been synthesized by addition of the isocopal-12-en-15-yl radical to a 3-hydroxy-2-methylene alkenenitrile, stereoselective elimination of acetic acid from the acetylated adducts, and reduction of the cyano group into a methyl
