201799-09-9

Upstream product

• 201670-50-0 (Z)-3-Bromo-8-(tert-butyl-diphenyl-silanyloxy)-2,6-dimethyl-oct-6-en-2-ol 
• 201670-52-2 (Z)-8-(tert-Butyl-diphenyl-silanyloxy)-2,6-dimethyl-oct-6-ene-2,3-diol 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 201670-51-1 (Z)-1-(tert-butyldiphenylsilyloxy)-6,7-epoxy-3,7-dimethylocta-2-ene 
• 139109-03-8 (Z)-1-[(tert-butyldiphenylsilyl)oxy]-3,7-dimethyl-2,6-octadiene 
• 139109-04-9 (Z)-1-[(tert-butyldiphenylsilyl)oxy]-3-methyl-2-hexen-6-al 
• 106-25-2 Nerol 
• 139108-85-3 isocopalenyl iodide 
• 139108-89-7 (Z)-8-(tert-Butyl-diphenyl-silanyloxy)-3-hydroxy-6-methyl-2-methylene-oct-6-enoic acid methyl ester 
• 16633-24-2 (10R,14S)-(+)-isoagath-12-en-15-ol 

Downstream Products

• 139108-91-1 (2E,6Z)-8-(tert-Butyl-diphenyl-silanyloxy)-6-methyl-2-[2-((1S,4aS,4bR,8aR,10aR)-2,4b,8,8,10a-pentamethyl-1,4,4a,4b,5,6,7,8,8a,9,10,10a-dodecahydro-phenanthren-1-yl)-ethyl]-octa-2,6-dienoic acid methyl ester 
• 139109-07-2 (2Z,6Z)-8-(tert-Butyl-diphenyl-silanyloxy)-6-methyl-2-[2-((1S,4aS,4bR,8aR,10aR)-2,4b,8,8,10a-pentamethyl-1,4,4a,4b,5,6,7,8,8a,9,10,10a-dodecahydro-phenanthren-1-yl)-ethyl]-octa-2,6-dienoic acid methyl ester 
• 139109-01-6 tert-Butyl-[(2Z,6E)-7-chloromethyl-3-methyl-9-((1S,4aS,4bR,8aR,10aR)-2,4b,8,8,10a-pentamethyl-1,4,4a,4b,5,6,7,8,8a,9,10,10a-dodecahydro-phenanthren-1-yl)-nona-2,6-dienyloxy]-diphenyl-silane 
• 139109-00-5 (2E,6Z)-8-(tert-Butyl-diphenyl-silanyloxy)-6-methyl-2-[2-((1S,4aS,4bR,8aR,10aR)-2,4b,8,8,10a-pentamethyl-1,4,4a,4b,5,6,7,8,8a,9,10,10a-dodecahydro-phenanthren-1-yl)-ethyl]-octa-2,6-dien-1-ol 
• 139236-71-8 tert-Butyl-[(2Z,6Z)-3,7-dimethyl-9-((1S,4aS,4bR,8aR,10aR)-2,4b,8,8,10a-pentamethyl-1,4,4a,4b,5,6,7,8,8a,9,10,10a-dodecahydro-phenanthren-1-yl)-nona-2,6-dienyloxy]-diphenyl-silane 

Relevant academic research and scientific papers

Synthesis of tricyclopolyprenols via a radical addition and a stereoselective elimination, part II: (Z)-tricyclopentaprenol, (E,E)- and (Z,Z)-tricyclohexaprenol, (Z,Z,Z)-tricycloheptaprenol

Four tricyclopolyprenols have been synthesised by addition of the isocopalenyl radical either to a 2-methylene-3-hydroxy alkenenitrile (in the case of (E,E)-tricyclohexaprenol) or to a methyl 2-methylene-3-hydroxy alkenoate (in the case of the three (Z)-t

A radical-based synthesis of (Z,Z)-tricyclohexaprenol

Addition of the isocopal-12-15-yl radical to a methyl 3-hydroxy-2-methylene alkenoate and stereoselective elimination of methanesulphonic acid from the mesylated adducts are the key steps of this synthesis of (Z,Z)-tricyclohexaprenol.