20202-28-2Relevant academic research and scientific papers
The reaction of superoxide with cinnamyl bromide: The surprising formation of an ether and an epoxy acetal
Frimer, Aryeh A.,Strul, Gila,Gilinsky-Sharon, Pessia
, p. 6337 - 6342 (1995)
The reaction of O2-· (KO2/18-crown-6 in toluene) with cinnamyl bromide yielded neither the expected cinnamyl peroxide nor its Kornblum-DeLaMare fragmentation products, cinnamaldehyde (4) and cinnamyl alcohol. Instead we ob
Synthetic Routs to the Piperolides, Faydenolides, Epoxypiperolides, and Related Compounds
Pelter, Andrew,Al-Bayati, Redha I. H.,Ayoub, Miqdad T.,Lewis, Wynn,Pardasani, Pushpa,Hansel, Rudolf
, p. 717 - 742 (2007/10/02)
Syntheses of the piperolides, the faydenolides, epoxypiperolide, and related compounds are described. (+/-)-Narthogenin is also efficiently produced.
ALKALINE FLUORIDE-m-CHLOROPEROXYBENZOIC ACID SYSTEMS AS MODULATED OXIDATION REAGENTS: EPOXIDATION OF α,β-UNSATURATED ACETALS
Camps, Francisco,Coll, Jose,Messeguer, Angel,Pujol, Ferran
, p. 971 - 974 (2007/10/02)
High yields (80-96percent) of epoxides of α,β-unsaturated acetals can be obtained by the use of suitable KF:NaF:m-CPBA mixtures as modulated oxidation reagents.
