The reaction of superoxide with cinnamyl bromide: The surprising formation of an ether and an epoxy acetal

DOI: 10.1016/0040-4020(95)00274-C

Source and publish data:

Tetrahedron p. 6337 - 6342 (1995)

Update date:2022-08-05

Topics:

Authors:

Frimer, Aryeh A.

Strul, Gila

Gilinsky-Sharon, Pessia

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Article abstract of DOI:10.1016/0040-4020(95)00274-C

The reaction of O₂^-· (KO₂/18-crown-6 in toluene) with cinnamyl bromide yielded neither the expected cinnamyl peroxide nor its Kornblum-DeLaMare fragmentation products, cinnamaldehyde (4) and cinnamyl alcohol. Instead we ob

Full text of DOI:10.1016/0040-4020(95)00274-C

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