20231-38-3Relevant academic research and scientific papers
3-Butenyloxycarbonyl as a new hydroxyl protecting group in carbohydrate synthesis
Zeng, Nana,Niu, Youhong,Ye, Xin-Shan
supporting information, p. 2935 - 2938 (2016/06/14)
3-Butenyloxycarbonyl (Bloc) has been identified as a new hydroxyl protecting group, which can be introduced under mild conditions in high yields and selectively removed by OsO4/NaIO4/2,6-lutidine in CH3CN-H2O wi
Intramolecular base-free sonogashira reaction for the synthesis of benzannulated chiral macrocycles embedded in carbohydrate templates
Hussain, Altaf,Yousuf, Syed Khalid,Kumar, Deepak,Lambu, Malikharjunarao,Singh, Baldev,Maity, Sudip,Mukherjee, Debaraj
, p. 1933 - 1940 (2012/09/22)
A base-free, intramolecular Sonogashira reaction-based general approach has been established for the diversity-oriented synthesis (DOS) of fused bi- and tricyclic systems containing benzannulated, 10- to 13-membered chiral macrocycles embedded in carbohydrate templates. Macrocycles with different ring sizes have been prepared by pre-designing the chiral building blocks. Base-sensitive groups like acetyl and TBDPS survived the reaction conditions. Copyright
Disaccharide-containing macrocycles by click chemistry and intramolecular glycosylation
Tiwari, Vinod K.,Kumar, Amit,Schmidt, Richard R.
, p. 2945 - 2956 (2012/07/27)
In this study o- and m-xylylene moieties in combination with a triazolylmethyl moiety have been successfully employed as a relatively rigid spacer system in intramolecular glycosylation reactions. Phenyl 3,4,6-tri-O-benzyl-2-O-propargyl-1-thio-D-glucopyra
