202798-29-6Relevant articles and documents
Synthesis of galactosaminyl d-chiro-inositols
Marnera, Georgia,d'Alarcao, Marc
, p. 1105 - 1116 (2007/10/03)
All six isomeric d-galactosaminopyranosyl-d-chiro-inositols have been prepared by glycosylation of appropriate penta-O-benzyl-d-chiro-inositols. The three requisite protected d-chiro-inositols were prepared by SmI2-promoted pinacol coupling of
Synthesis of new hexosaminyl D- and L-chiro-inositols related to putative insulin mediators
Cid, M. Belen,Bonilla, Julia B.,Alfonso, Francisco,Martin-Lomas, Manuel
, p. 3505 - 3514 (2007/10/03)
We have developed an efficient synthetic strategy to HexNH 2-α(1→3)-L-chiro-inositol (XII-XIII) and HexNH 2-α(1→2)-D-chiro-inositol (XIV-XV) based on the regio and stereoselective glycosylation of tetrabenzoyl-L-chiro-inositol 2 and
Ready routes to key myo-inositol component of GPIs employing microbial arene oxidation or Ferrier reaction
Jia, Zhaozhong J.,Olsson, Lars,Fraser-Reid, Bert
, p. 631 - 632 (2007/10/03)
Microbial arene oxidation or Ferrier reaction of enol acetates provides versatile complementary routes that greatly facilitate preparation of inositol synthon(s) for GPI assembly.
Synthesis of a jojoba bean disaccharide
Kornienko, Alexander,Marnera, Georgia,D'Alarcao, Marc
, p. 141 - 144 (2007/10/03)
A synthesis of the disaccharide recently isolated from jojoba beans, 2-O-α-D-galactopyranosyl-D-chiro-inositol, has been achieved. The suitably protected chiro-inositol unit was prepared by an enantiospecific synthesis from L-xylose utilizing SmI2-mediated pinacol coupling as a key step. Copyright (C) 1998 Elsevier Science Ltd.