203056-65-9Relevant academic research and scientific papers
Gold(I)-Catalyzed Desymmetrization of 1,4-Dienes by an Enantioselective Tandem Alkoxylation/Claisen Rearrangement
Wu, Hongmiao,Zi, Weiwei,Li, Guigen,Lu, Hongjian,Toste, F. Dean
, p. 8529 - 8532 (2015)
An enantioselective alkoxylation/Claisen rearrangement reaction was achieved by a strategic desymmetrization of 1,4-dienes under the catalysis of (S)-DTBM-Segphos(AuCl)2/AgBF4. This reaction system was highly selective for the format
Direct furan formation by treatment of alkynyl ketones with strong potassium bases
MaGee, David I.,Leach, James D.,Setiadji, Santosa
, p. 2847 - 2856 (1999)
The reaction of keto-alkynes with strong potassium bases such as KOtBu, KHMDS or KH yields substituted furans in moderate to good yields without any special activation of the alkyne required. The method offers both a flexibility and rapid method for the s
