20306-76-7

Upstream product

• 60732-17-4 2,5-dimethoxybenzyl bromide 
• 75-16-1 methylmagnesium bromide 
• 61176-68-9 Aethyl-2,3,6-tridesoxy-α-L-glycero-hex-2-enopyranosid-4-ulose 
• 24599-58-4 2,5-dimethoxy toluene 
• 3840-27-5 2,5-dimethoxybenzyl chloride 

Downstream Products

• 120475-75-4 1,2-bis<4-(chloromethyl)-2,5-dimethoxyphenyl>ethane 
• 10365-14-7 1.2-Bis(2.5-dihydroxyphenyl)ethane 
• 214221-65-5 1,2-bis(4-bromo-2,5-dimethoxyphenyl)ethane 
• 20452-50-0 [2-(1,4-benzoquinonyl)ethyl]-1,4-benzoquinone 
• 120475-74-3 2,2'-ethylenebis<2,5-dimethoxybenzyl alcohol> bis(hydrogen succinate) 
• 120475-63-0 2,2'-ethylenebis[5-(hydroxymethyl)-1,4-benzoquinone]bis(hydrogen succinate) 
• 120475-72-1 1,2-bis<4-(bromomethyl)-2,5-dimethoxyphenyl>ethane 
• 120475-76-5 1,2-bis<4-(hydroxymethyl)-2,5-dimethoxyphenyl>ethane 
• 120475-61-8 2,2'-ethylenebis[5-(bromomethyl)-1,4-benzoquinone] 

Relevant academic research and scientific papers

Addition of organolithium reagents to some carbohydrate enones

Addition of organolithium reagents to die sugar enones: alkyl 2,3,6-trideoxy-α-L- and 2,3-dideoxy-α- D-hex-2-enopyranosid-4-ulose has been examined. Butyl, benzyl and 2,5-dimethoxy-4-methylphenyllithium add, with increasing stereoselectivity, to the carbonyl group of the α,β-unsaturated ketosugars, whereas 2,5-dimethoxybenzyllithium undergoes stereospecific conjugate addition and 1,2-addition in die ratio of 1.7:1. The structure of the resultant carbinols is based on X-ray crystallographic evidence.

Mono and bis(bioreductive) alkylating agents: Synthesis and antitumor activities in a B16 melanoma model

Several potentially bis(alkylating) bis(quinones) (3-5) and 1,4- and 1,3-bis(alkylating) monoquinones (6-13) belonging to general structure 2,2'-ethylenebis[5-[(leaving group) methyl]-1,4-benzoquinone] (3-5) and 2,5- and 2,6-bis[(leaving group)methyl]-1,4