203392-27-2Relevant articles and documents
Synthesis of Morita–Baylis–Hillman-fluorides using 1,1,2,2-tetrafluoroethyl-N,N-dimethylamine
Sumii, Yuji,Nagasaka, Takato,Matsuno, Ayaka,Hayashi, Hidetoshi,Mimura, Hideyuki,Kagawa, Takumi,Shibata, Norio
, (2021/08/18)
Morita–Baylis–Hillman (MBH)-fluorides are valuable platforms for asymmetric allylic substitution reactions. However, the preparation of MBH-fluorides requires the use of an explosive fluorinating reagent, namely (diethylamino)sulfur trifluoride (DAST). Th
Enantioselective Trichloromethylation of MBH-Fluorides with Chloroform Based on Silicon-assisted C-F Activation and Carbanion Exchange Induced by a Ruppert-Prakash Reagent
Nishimine, Takayuki,Taira, Hiromi,Tokunaga, Etsuko,Shiro, Motoo,Shibata, Norio
supporting information, p. 359 - 363 (2016/01/25)
Enantioselective trichloromethylation of Morita-Baylis-Hillman (MBH)-type allylic fluorides with chloroform (HCCl3) under organocatalysis was achieved with high to excellent enantioselectivities. Silicon-assisted C-F bond activation by a Rupper
First 1,3-dipolar cycloaddition of Z-α-phenyl-N-methylnitrone with allylic fluorides: A stereoselective route to enantiopure fluorine-containing isoxazolidines and amino polyols
Bernardi, Luca,Bonini, Bianca F.,Comes-Franchini, Mauro,Fochi, Mariafrancesca,Folegatti, Mahena,Grilli, Stefano,Mazzanti, Andrea,Ricci, Alfredo
, p. 245 - 250 (2007/10/03)
Enantiopure fluorinated isoxazolidines and amino polyols were obtained from the 1,3-dipolar cycloaddition of allylic fluorides and Z-α-phenyl-N- methylnitrone under environment-friendly conditions.
