20365-71-3Relevant academic research and scientific papers
Et3N mediated synthesis of polysubstituted thiophenes from α-oxo ketene dithioacetals
Kan, Xiaoli,Yang, Xiaobing,Hu, Fangzhong,Wang, Yang,Liu, Ying,Zou, Xiaomao,Li, Hengyu,Li, Hao,Zhang, Qichun
, p. 6198 - 6201 (2015)
In this Letter, an efficient synthetic route to prepare polysubstituted thiophene derivatives was achieved via the Et3N-mediated (Claisen) rearrangement reaction from α-oxo S-methyl-S-propargyl ketenes, which were obtained through alkylation of
Influence of the ligand frameworks on the coordination environment and properties of new phenylmercury(II) β-oxodithioester complexes
Rajput, Gunjan,Yadav, Manoj Kumar,Drew, Michael G. B.,Singh, Nanhai
, p. 5909 - 5916 (2015)
New phenylmercury(ii) complexes of the form [PhHg(L1), PhHg(L2) and PhHg(L3)] (L1 = methyl-3-hydroxy-3-(p-methoxyphenyl)-2-propenedithioate (1), L2 = methyl-3-hydroxy-3-(p-bromophenyl)-2-propenedithioate (2) and L3 = methyl-3-hydroxy-(3-pyridyl)-2-propene
New planar trans-copper(II) β-dithioester chelate complexes: synthesis, characterization, anticancer activity and DNA-binding/cleavage studies
Yadav, Manoj Kumar,Maurya, Akhilendra Kumar,Rajput, Gunjan,Manar, Krishna Kumar,Vinayak, Manjula,Drew, Michael G. B.,Singh, Nanhai
, p. 565 - 583 (2017)
New planar trans-copper(II) β-dithioester complexes, [Cu(L)2] (L?=?methyl-3-hydroxy-(3-pyridyl)-2-propenedithioate (L1 in 1), methyl-3-hydroxy-(2-naphthyl)-2-propenedithioate (L2 in 2), methyl-3-hydroxy-3-(p-methoxyphenyl)-2-propenedithioate (L
Synthesis and characterization of new square planar heteroleptic cationic complexes [Ni(ii) β-oxodithioester-dppe]+; Their use as a catalyst for Chan-Lam coupling
Kumari, Kavita,Kumar, Saurabh,Singh, Krishna Nand,Drew, Michael G. B.,Singh, Nanhai
, p. 12143 - 12153 (2020/07/30)
Novel heteroleptic [Ni(ii) β-oxodithioester-dppe]+PF6- complexes (β-oxodithioester = methyl-3-hydroxy-3-benzyl-2-propenedithioate L1 1, methyl-3-hydroxy-3-(p-methoxyphenyl)-2-propenedithioate L2 2, methyl-3-hydroxy-3-(naphthyl)-2-propenedithioate L3 3, methyl-3-hydroxy-3-(p-chlorophenyl)-2-propenedithioate L4 4, methyl-3-hydroxy-3-(p-bromophenyl)-2-propenedithioate L5 5 and methyl-3-hydroxy-3-(p-cyanophenyl)-2-propenedithioate L6 6) have been synthesized and characterized by elemental (C, H, N) analysis, ESI-MS, IR, UV-visible, 1H, 13C{1H}, 31P{1H} and 19F{1H} NMR spectroscopy. The distorted square planar structures of the isomorphous cationic complexes 2, 3, 4 and 5 have been determined by X-ray crystallography. The catalytic activities of 1-6 were investigated for the Chan-Lam coupling reaction involving arylboronic acids and amines to afford N-arylated products in good to excellent yields under mild conditions with 1 mol% catalyst loading. This catalytic protocol offers significant functional group tolerance, and is endowed with a broad substrate scope. This journal is
Catalytic activity of new heteroleptic [Cu(PPh3)2(β-oxodithioester)] complexes: Click derived triazolyl glycoconjugates
Kumari, Kavita,Singh, Anoop S.,Manar, Krishna K.,Yadav, Chote Lal,Tiwari, Vinod K.,Drew, Michael G.B.,Singh, Nanhai
supporting information, p. 1166 - 1176 (2019/01/21)
A series of four new and two known luminescent heteroleptic Cu(i) complexes of the form [Cu(PPh3)2(β-oxodithioester)] (β-oxodithioester = methyl-3-hydroxy-3-(2-furyl)-2-propenedithioate L1 1, methyl-3-hydroxy-3-(2-thienyl)-2-propened
Half-sandwich titanium complexes with β-oxodithioester ligands
Mancilla-González, María Del Carmen,Jancik, Vojtech,Martínez-Otero, Diego,Moya-Cabrera, Mónica,García-Orozco, Iván
, p. 35 - 41 (2015/02/19)
The reaction of CpTiCl3with HLx[HLx= methyl 3-(4′-X-phenyl)-3-hydroxy-2-propenedithioate ligands; X = H(1), Me(2), OMe(3), Cl(4), Br(5)] in the presence of NEt3yielded the corresponding half-sandwich complexes T
An expedient route to highly functionalized 2H-chromene-2-thiones via ring annulation of β-oxodithioesters catalyzed by InCl3 under solvent-free conditions
Verma, Rajiv Kumar,Verma, Girijesh K.,Raghuvanshi, Keshav,Singh, Maya Shankar
experimental part, p. 584 - 589 (2011/03/18)
A convenient and one-pot synthesis of 3-aroyl/heteroaroyl-2H-chromene-2- thiones and benzo[f]2H-chromene-2-thiones has been developed by the condensation of β-oxodithioesters and salicylaldehydes/α-hydroxynaphthaldehydes in the presence of indium trichlor
