204070-27-9

Upstream product

• 56083-15-9 (S)-4-((allyloxy)methyl)-2,2-dimethyl-1,3-dioxolane 
• 73097-87-7 2-hydroxy-3-(prop-2-en-1-yloxy)propyl benzoate 
• 123-34-2 3-allyloxy-1,2-propanediol 
• 769-78-8 vinyl benzoate 
• 123-34-2 (R)-3-allyloxypropane-1,2-diol 
• 98-88-4 benzoyl chloride 

Downstream Products

• 204070-34-8 Benzoic acid (S)-3-allyloxy-2-((3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-propyl ester 
• 204070-40-6 (R)-3-Allyloxy-2-((3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-propan-1-ol 
• 204070-61-1 (3R,4S,5R,6R)-2-((R)-1-Allyloxymethyl-2-dodecyloxy-ethoxy)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran 
• 204070-55-3 (3R,4S,5R,6R)-2-((R)-1-Allyloxymethyl-2-tetradecyloxy-ethoxy)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran 
• 204070-51-9 (3R,4S,5R,6R)-2-((R)-1-Allyloxymethyl-2-hexadecyloxy-ethoxy)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran 
• 204070-44-0 (3R,4S,5R,6R)-2-((R)-1-Allyloxymethyl-2-octadecyloxy-ethoxy)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran 

Relevant academic research and scientific papers

Enzymatic synthesis of both enantiomeric forms of 3-allyloxy-propane-1,2- diol

The stereoselective synthesis of (S)- and (R)-3-allyloxy-propane-1,2-diol has been accomplished in four steps from (RS)-3-allyloxy-propane-1,2-diol. Only one intermediate, namely 1-benzoyloxy-3-allyloxy-2-propanone has been prepared by a chemical reaction, that is, pyridinium chlorochromate oxidation of 1-benzoyloxy-3-allyloxypropan-2-ol. All of the remaining reactions (regioselective acylations, asymmetric bioreduction of prochiral ketones, and enzymatic alcoholysis) have been carried out in the presence of biocatalysts.