20432-46-6Relevant academic research and scientific papers
ACYLATION OF 1,3-ALKADIENES BY ACYL FLUOROSULFONATES. STEREOSPECIFIC SYNTHESIS OF E AND Z ISOMERS OF CONJUGATED DIENONES
Gavrishova, T.I.,Shastin, A.V.,Balenkova, E.S.
, p. 580 - 583 (2007/10/02)
Acyl fluorosulfonates generated from acyl fluorides and SO3 permits acylation of butadiene and isoprene to give triconjugated dienones.This reaction proceeds stereospecifically and leads to E isomers of the corresponding dienones in the case of butadiene and Z isomers in the case of isoprene.
Une synthese hautement stereoselective de dienes conjugues (E)
Bloch, R.,Abecassis, J.,Hassan, D.
, p. 2019 - 2024 (2007/10/02)
A general method for the preparation of (E) terminal conjugated dienes was developed by the flash thermolysis of 2-substituted 2,5-dihydrothiophene-1,1-dioxides generated by a retro Diels-Alder reaction.This process allows the obtention of conjugated dienes, bearing or not a functionality (alcohols, esters), with an excellent stereoisomeric purity (in general higher than 98percent).An application to the synthesis of (E)-9,11-dodecadien-1-yl acetate, the major component of the sex pheromone of Diparopsis castanea, shows the generality and the efficacy of this method.
