204587-98-4Relevant academic research and scientific papers
Diastereoselective synthesis of aziridine esters via amino selanyl esters
Miniejew, Catherine,Outurquin, Francis,Pannecoucke, Xavier
, p. 2657 - 2670 (2007/10/03)
A synthesis of aziridine esters based on the cyclisation of amino selanyl esters induced by the selanyl group activation was developed with either the Meerwein salt or NBS. Two asymmetric approaches are proposed: the diastereoselective reductions of α-sel
A new asymmetric synthesis of 2,6-cis-disubstituted 4-methylenepiperidines: Total synthesis of (+)-alkaloid 241D and (+)-isosolenopsin A
Monfray, Jeremy,Gelas-Mialhe, Yvonne,Gramain, Jean-Claude,Remuson, Roland
, p. 1025 - 1034 (2007/10/03)
A highly diastereoselective synthesis of 2,6-cis-disubstituted-4- methylenepiperidines based on a Mannich type intramolecular cyclization of an allylsilane on an iminium ion is described. The synthetic potential of this methodology is demonstrated by the
A facile enantioselective synthesis of 2-(2-aminoethyl)allylsilanes, new synthons for piperidine synthesis
Monfray, Jérémy,Gelas-Mialhe, Yvonne,Gramain, Jean-Claude,Remuson, Roland
, p. 5785 - 5787 (2007/10/03)
The synthesis of chiral (2-substituted-2-aminoethyl)allylsilanes by cerium mediated trimethylsilylmethylmagnesium chloride addition to the ester group of non racemic chiral β-aminoesters is described.
