20514-52-7

Basic information

• Product Name: 3-cyclohexyl-2-methylpropanal
• CAS NO: 20514-52-7
• Molecular Formula: C₁₀H₁₈O
• Molecular Weight: 154.2493
• Mol File: 20514-52-7.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 223.6°C at 760 mmHg
• Flash Point: 85.9°C
• Density: 0.882g/cm³
• Vapor Pressure: 0.0953mmHg at 25°C
• Refractive Index: 1.443
• CAS DataBase Reference: 3-cyclohexyl-2-methylpropanal(CAS DataBase Reference)
• NIST Chemistry Reference: 3-cyclohexyl-2-methylpropanal(20514-52-7)
• EPA Substance Registry System: 3-cyclohexyl-2-methylpropanal(20514-52-7)

Safety Data

• Hazardous Substances Data: 20514-52-7(Hazardous Substances Data)

Upstream product

• 39575-65-0 2-isopropenyl-4,4,6-trimethyl-5,6-dihydro-4H-[1,3]oxazine 
• 931-50-0 cyclohexylmagnesium bromide 
• 60218-00-0 Diethyl-(3-cyclohexyl-2-methyl-1-propenyloxy)boran 
• 78-85-3 2-methylpropenal 
• 110-83-8 cyclohexene 
• 201230-82-2 carbon monoxide 
• 5364-83-0 1-cyclohexylprop-1-ene 
• 2043-61-0 cyclohexanecarbaldehyde 
• 626-62-0 Cyclohexyl iodide 

Downstream Products

• 76019-90-4 2-methyl-3-cyclohexylpropanol 

Relevant articles and documents

Phosphabarrelenes as ligands in rhodium-catalyzed hydroformylation of internal alkenes essentially free of alkene isomerization

Despite significant research efforts in the past, one of the remaining problems to be solved in industrially important hydroformylation is the chemoselective low-pressure hydroformylation of internal alkenes. We report here on a new class of phosphabarrelene/rhodium catalysts 2 that display very high activity towards hydroformylation of internal alkenes with an unusually low tendency towards alkene isomerization. Preparation of new phosphabarrelene ligands, studies of their coordination properties, as well as results obtained in the rhodium-catalyzed hydroformylation of cyclic and acyclic internal alkenes are reported.

TRIS(TRIMETHYLSILYL)SILANE AS MEDIATOR IN ORGANIC SYNTHESIS VIA RADICALS

Silane 3 is an effective mediator in organic synthesis via radicals.Reactions with this silane give smaller amounts of unwanted reduction products than reactions with toxic stannanes.