205372-01-6

Basic information

• Product Name: (2S,4R)-4-Benzyloxy-hept-6-ene-1,2-diol
• Synonyms: (2S,4R)-4-Benzyloxy-hept-6-ene-1,2-diol
• CAS NO: 205372-01-6
• Molecular Weight: 236.311
• Mol File: 205372-01-6.mol

Chemical Properties

• CAS DataBase Reference: (2S,4R)-4-Benzyloxy-hept-6-ene-1,2-diol(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,4R)-4-Benzyloxy-hept-6-ene-1,2-diol(205372-01-6)
• EPA Substance Registry System: (2S,4R)-4-Benzyloxy-hept-6-ene-1,2-diol(205372-01-6)

Safety Data

• Hazardous Substances Data: 205372-01-6(Hazardous Substances Data)

Upstream product

• 153946-95-3 (2S,4R)-1-(tert-Butyl-diphenyl-silanyloxy)-hept-6-ene-2,4-diol 
• 100-39-0 benzyl bromide 
• 87318-96-5 (4S)-4-((2R)-2-hydroxypent-4-enyl)-2,2-dimethyl-1,3-dioxolane 
• 765300-83-2 (R)-(S)-1-(1,4-Dioxa-spiro[4.5]dec-2-yl)-pent-4-en-2-ol 
• 765300-84-3 (S)-2-((R)-2-Benzyloxy-pent-4-enyl)-1,4-dioxa-spiro[4.5]decane 
• 205372-00-5 ((4S,6R)-6-Allyl-2-phenyl-[1,3]dioxan-4-yl)-methanol 

Downstream Products

• 205372-02-7 2,2-Dimethyl-propionic acid (2S,4R)-4-benzyloxy-2-(tert-butyl-dimethyl-silanyloxy)-hept-6-enyl ester 
• 765300-80-9 6-benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-8-(tert-butyl-diphenyl-silanyloxy)-2-methyl-decanoic acid 
• 765300-79-6 6-benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-8-(tert-butyl-diphenyl-silanyloxy)-2-methyl-decanal 
• 765300-54-7 3-(tert-butyl-dimethyl-silanyloxy)-8-(tert-butyl-diphenyl-silanyloxy)-6-hydroxy-2-methyl-decanoic acid 
• 765300-81-0 (3S,4R,7R)-4-(tert-Butyl-dimethyl-silanyloxy)-7-[(R)-2-(tert-butyl-diphenyl-silanyloxy)-butyl]-3-methyl-oxepan-2-one 
• 765300-89-8 (4R,6R)-4-Benzyloxy-6-(tert-butyl-diphenyl-silanyloxy)-octan-1-ol 
• 765300-55-8 (4R,6R)-4-Benzyloxy-6-(tert-butyl-diphenyl-silanyloxy)-octanal 
• 765300-88-7 ((1R,3R)-3-Benzyloxy-1-ethyl-hex-5-enyloxy)-tert-butyl-diphenyl-silane 
• 765300-87-6 (3R,5R)-5-Benzyloxy-oct-7-en-3-ol 
• 765300-86-5 (S)-2-((R)-2-Benzyloxy-pent-4-enyl)-oxirane 
• 765300-85-4 Toluene-4-sulfonic acid (2S,4R)-4-benzyloxy-2-hydroxy-hept-6-enyl ester 
• 1028224-73-8 2,2-Dimethyl-propionic acid (2S,4R)-4-benzyloxy-2-hydroxy-hept-6-enyl ester 

Relevant articles and documents

Studies directed towards the total synthesis of feigrisolide B

Attempts directed towards the total synthesis of feigrisolide B resulted in the synthesis of lactones 1 and 2. The synthesis of 1 and 2 was achieved from d-glucose and l-malic acid, respectively, with a Ti(IV) mediated diastereoselective aldol reaction as

Studies on the stereochemistry of theonezolides A-C1: Elucidation of the relative configurations of 1,3-diol moieties of the C-4 ～ C-17 fragment

Four model compounds having syn and anti 1,3-diol type moieties corresponding to C-8/C-10 and C-14/C-16 positions contained in the C-4 ～ C-17 fragment of theonezolides A-C were prepared. Comparison of their spectral data suggested that the 1,3-diol at C-8/C-10 and the OH/OMe groups at C-14/C-16 positions of theonezolides A-C were both syn.

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